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dc.contributor.authorVanden Broeck, Sofie M. P.
dc.contributor.authorNelson, David J.
dc.contributor.authorCollado, Alba
dc.contributor.authorFalivene, Laura
dc.contributor.authorCavallo, Luigi
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorVan Hecke, Kristof
dc.contributor.authorNahra, Fady
dc.contributor.authorCazin, Catherine S. J.
dc.contributor.authorNolan, Steven Patrick
dc.date.accessioned2022-05-13T23:50:16Z
dc.date.available2022-05-13T23:50:16Z
dc.date.issued2021-05-14
dc.identifier.citationVanden Broeck , S M P , Nelson , D J , Collado , A , Falivene , L , Cavallo , L , Cordes , D B , Slawin , A M Z , Van Hecke , K , Nahra , F , Cazin , C S J & Nolan , S P 2021 , ' Synthesis of gold(I)-trifluoromethyl complexes and their role in generating spectroscopic evidence for a gold(I)-difluorocarbene species ' , Chemistry - A European Journal , vol. Early View . https://doi.org/10.1002/chem.202100195en
dc.identifier.issn0947-6539
dc.identifier.otherPURE: 273733769
dc.identifier.otherPURE UUID: ff1cc0a4-f735-49b8-82bf-2a19efb02923
dc.identifier.otherRIS: urn:6A45E9550D5E2B04E8AE1C061743E098
dc.identifier.otherORCID: /0000-0002-9527-6418/work/94291593
dc.identifier.otherORCID: /0000-0002-5366-9168/work/94291602
dc.identifier.otherScopus: 85105875392
dc.identifier.otherWOS: 000650226600001
dc.identifier.urihttps://hdl.handle.net/10023/25374
dc.descriptionWe thank the Ghent University (IoF), the Special Research Fund (BOF) starting (SPN, CSJC) and advanced (SPN, KVH) grants and Research Foundation Flanders (FWO) (fellowship to SVB and grant to CSJC and KVH) for funding.en
dc.description.abstractReadily-prepared and bench-stable [Au(CF3)(NHC)] compounds were synthesized using new methodologies, starting from [Au(OH)(NHC)], [Au(Cl)(NHC)] or [Au(L)(NHC)]HF2 precursors (NHC = N-heterocyclic carbene). The mechanism of formation of these species was investigated. Consequently, a new and straightforward strategy for the mild and selective cleavage of a single carbon-fluorine bond from [Au(CF3)(NHC)] complexes was attempted and found to be reversible in the presence of an additional nucleophilic fluoride source. This straightforward technique has led to the unprecedented spectroscopic observation of a gold(I)-NHC difluorocarbene species.
dc.language.isoeng
dc.relation.ispartofChemistry - A European Journalen
dc.rightsCopyright © 2021 Wiley‐VCH GmbH. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1002/chem.202100195en
dc.subjectDifluorocarbeneen
dc.subjectTrifluoromethylen
dc.subjectN-heterocyclic carbeneen
dc.subjectGold(I)en
dc.subjectFluoride abstractionen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSynthesis of gold(I)-trifluoromethyl complexes and their role in generating spectroscopic evidence for a gold(I)-difluorocarbene speciesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/chem.202100195
dc.description.statusPeer revieweden
dc.date.embargoedUntil2022-05-14


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