Measurements of microwave and NMR spectra for 15N substituted formamidinium formate
Date
14/05/2021Metadata
Show full item recordAbstract
A sample of doubly-substituted 15N formamidinium formate was synthesized and the microwave spectrum was measured in the 5.6-14.2GHz frequency range using a Flygare-Balle type pulsed beam Fourier transform microwave (MW) spectrometer. A total of 13 a-type rotational transitions were measured and fitted to obtain the rotational constants and centrifugal distortion constants for the 15N substituted isotopologue. The rotational constants and centrifugal distortion constants determined have the following values: A=5808.02(18)MHz, B=2127.008(2)MHz, C=1557.615(2)MHz, DJ=0.60(11)kHz, DJK=4.95(71)kHz and δJ = -0.138(24)kHz. Tunneling splittings were searched for, but not observed. NMR spectra for this compound are reported including values of δC, δN, 1JCH, 1JCN and 2JNH in CD3SOCD3, CD3OD and D2O. The occurrence of NH to ND exchange in D2O allowed the fortuitous measurement of 1JND.
Citation
Zhou , Z , Peureux , C , Aitken , R A & Kukolich , S J 2021 , ' Measurements of microwave and NMR spectra for 15 N substituted formamidinium formate ' , Journal of Molecular Spectroscopy , vol. 378 , 111478 . https://doi.org/10.1016/j.jms.2021.111478
Publication
Journal of Molecular Spectroscopy
Status
Peer reviewed
ISSN
0022-2852Type
Journal article
Rights
Copyright © 2021 Elsevier Inc. All rights reserved. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1016/j.jms.2021.111478
Description
This material is based upon work supported by the National Science Foundation under Grant Nos. CHE-1057796 and CHE-1952289 at the University of Arizona.Collections
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