Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3
Abstract
In the title compound, the oxalate ligand simultaneously bridges both Mn-centred and Na-centred octahedra to produce a unique ‘doubly-interpenetrated’ perovskite-like lattice with an unconventional octahedral tilt system. In turn, the coordination requirements of the oxalate ligand lead to a rare ‘twisted’ conformation.
Citation
He , X , Zhang , X , Ji , B , Yao , W , Lightfoot , P & Tang , Y 2021 , ' Tilting and twisting in a novel perovzalate, K 3 NaMn(C 2 O 4 ) 3 ' , Chemical Communications , vol. 57 , no. 20 , pp. 2567-2570 . https://doi.org/10.1039/d1cc00085c
Publication
Chemical Communications
Status
Peer reviewed
ISSN
1359-7345Type
Journal article
Rights
Copyright © 2021 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D1CC00085C
Description
We acknowledge support from the National Natural Science Foundation of China (22005329, 52061160484, 51822210, 51972329), Newton International Fellowships Alumni 2018/2019 (AL\180020, AL\191011), Key Area Research and Development Program of Guangdong Province (2019B090914003), Shenzhen Science and Technology Planning Project (No. JCYJ20180507182512042, JCYJ20190807172001755, JCYJ20200109115624923), and Science and Technology Planning Project of Guangdong Province (2019A1515110975, 2019A1515011902, 2019TX05L389).Collections
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.