Tilting and twisting in a novel perovzalate, K3NaMn(C2O4)3
Abstract
In the title compound, the oxalate ligand simultaneously bridges both Mn-centred and Na-centred octahedra to produce a unique ‘doubly-interpenetrated’ perovskite-like lattice with an unconventional octahedral tilt system. In turn, the coordination requirements of the oxalate ligand lead to a rare ‘twisted’ conformation.
Citation
He , X , Zhang , X , Ji , B , Yao , W , Lightfoot , P & Tang , Y 2021 , ' Tilting and twisting in a novel perovzalate, K 3 NaMn(C 2 O 4 ) 3 ' , Chemical Communications , vol. 57 , no. 20 , pp. 2567-2570 . https://doi.org/10.1039/d1cc00085c
Publication
Chemical Communications
Status
Peer reviewed
ISSN
1359-7345Type
Journal article
Description
We acknowledge support from the National Natural Science Foundation of China (22005329, 52061160484, 51822210, 51972329), Newton International Fellowships Alumni 2018/2019 (AL\180020, AL\191011), Key Area Research and Development Program of Guangdong Province (2019B090914003), Shenzhen Science and Technology Planning Project (No. JCYJ20180507182512042, JCYJ20190807172001755, JCYJ20200109115624923), and Science and Technology Planning Project of Guangdong Province (2019A1515110975, 2019A1515011902, 2019TX05L389).Collections
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.