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Isoreticular chemistry of scandium analogues of the multicomponent metal-organic framework MIL-142
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dc.contributor.author | Prasad, Ram R. R. | |
dc.contributor.author | Pleass, Charlotte | |
dc.contributor.author | Rigg, Amber | |
dc.contributor.author | Cordes, David Bradford | |
dc.contributor.author | Lozinska, Magdalena Malgorzata | |
dc.contributor.author | Georgieva, Veselina Mihaylova | |
dc.contributor.author | Hoffmann, Frank | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Wright, Paul Anthony | |
dc.date.accessioned | 2021-12-08T00:45:11Z | |
dc.date.available | 2021-12-08T00:45:11Z | |
dc.date.issued | 2020-12-08 | |
dc.identifier | 271738365 | |
dc.identifier | 5e2ba1bc-4979-437b-8979-439ca704dceb | |
dc.identifier | 85100258236 | |
dc.identifier | 000613496600006 | |
dc.identifier.citation | Prasad , R R R , Pleass , C , Rigg , A , Cordes , D B , Lozinska , M M , Georgieva , V M , Hoffmann , F , Slawin , A M Z & Wright , P A 2020 , ' Isoreticular chemistry of scandium analogues of the multicomponent metal-organic framework MIL-142 ' , CrystEngComm . https://doi.org/10.1039/D0CE01593H | en |
dc.identifier.issn | 1466-8033 | |
dc.identifier.other | ORCID: /0000-0002-4243-9957/work/85855022 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/85855080 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/85855099 | |
dc.identifier.other | ORCID: /0000-0002-8724-6358/work/85855357 | |
dc.identifier.uri | https://hdl.handle.net/10023/24485 | |
dc.description | RRRP and PAW thank the Engineering and Physical Sciences Research Council (EPSRC) and CRITICAT Centre for Doctoral Training for Financial Support [PhD studentship to RRRP; EP/L016419/1]. MML and PAW would also like to thank EPSRC for FLEXICCS grant (Versatile Adsorption Process for the Capture of Carbon Dioxide from Industrial Sources; EP/N024613/1). The research data supporting this publication can be accessed at: https://doi.org/10.17630/536b5f75-ce3c-414b-a336-497e00280158.56 | en |
dc.description.abstract | Interpenetrated multicomponent MIL-142(Sc) MOFs were synthesised using the planar tritopic (4,4’,4’’-(1,3,5-triazine-2,4,6-triyl)tribenzoate, TATB, or 4,4’,4’’-(pyridine-2,4,6-triyl)tribenzoate, PTB)) and linear ditopic (1,4-benzenedicarboxylate, BDC, or 2-amino or 2-nitro-1,4-benzenedicarboxylate (NH2- or NO2-BDC) linkers. Structure solution of the MIL-142(Sc)-TATB series from single crystal X-ray diffraction in space group R3 ̅m reveals regioselective ordering of bulky NO2 groups in MIL-142(Sc)-TATB-NO2. Use of 1,3,5-benzenetribenzoate (BTB) favours instead the mesoporous Sc-BTB, the PTB analogue of which forms in the absence of BDC. The materials are highly porous: MIL-142(Sc)-TATB-BDC has a pore volume of 0.70 cm3 g-1. | |
dc.format.extent | 11 | |
dc.format.extent | 2161716 | |
dc.language.iso | eng | |
dc.relation.ispartof | CrystEngComm | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Isoreticular chemistry of scandium analogues of the multicomponent metal-organic framework MIL-142 | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.1039/D0CE01593H | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2021-12-08 | |
dc.identifier.grantnumber | EP/N024613/1 | en |
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