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Solvothermal synthesis of a novel calcium metal-organic 2 framework : high temperature and electrochemical behaviour
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dc.contributor.author | Main, Russell Matthew | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Desai, Aamod V. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Wheatley, Paul | |
dc.contributor.author | Armstrong, A. Robert | |
dc.contributor.author | Morris, Russell E. | |
dc.date.accessioned | 2021-11-22T13:30:02Z | |
dc.date.available | 2021-11-22T13:30:02Z | |
dc.date.issued | 2021-11-22 | |
dc.identifier | 276750118 | |
dc.identifier | e6dc4a7d-2625-4d35-81ec-4de0dae4b42a | |
dc.identifier | 85119973479 | |
dc.identifier | 000727569800001 | |
dc.identifier.citation | Main , R M , Cordes , D B , Desai , A V , Slawin , A M Z , Wheatley , P , Armstrong , A R & Morris , R E 2021 , ' Solvothermal synthesis of a novel calcium metal-organic 2 framework : high temperature and electrochemical behaviour ' , Molecules , vol. 26 , no. 22 , 7048 . https://doi.org/10.3390/molecules26227048 | en |
dc.identifier.issn | 1420-3049 | |
dc.identifier.other | ORCID: /0000-0003-1937-0936/work/103865167 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/103865276 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/103865383 | |
dc.identifier.other | ORCID: /0000-0001-7809-0315/work/103865388 | |
dc.identifier.other | ORCID: /0000-0001-7219-3428/work/103865939 | |
dc.identifier.uri | https://hdl.handle.net/10023/24381 | |
dc.description | This research was funded by the European Research Council AdG grant number ADOR- 336 787073 and by the Faraday Institution (grant number FIRG018). | en |
dc.description.abstract | The rapid growth in the field of metal-organic frameworks (MOFs) over recent years has highlighted their high potential in a variety of applications. For biological and environmental applications MOFs with low toxicity are vitally important to avoid any harmful effects. For this reason, Ca-based MOFs are highly desirable owing to their low cost and high biocompatibility. Useful Ca MOFs are still rare owing to the ionic character and large size of the Ca2+ ion tending to produce dense phases. Presented here is a novel Ca-based MOF containing 2,3-dihyrdoxyterephthalate (2,3-dhtp) linkers Ca(2,3-dhtp)(H2O) (SIMOF-4). The material undergoes a phase transformation on heating, which can be followed by variable temperature powder X-ray diffraction. The structure of the high temperature form was obtained using single-crystal X-ray diffraction. The electrochemical properties of SIMOF-4 were also investigated for use in a Na ion battery. | |
dc.format.extent | 3844105 | |
dc.language.iso | eng | |
dc.relation.ispartof | Molecules | en |
dc.subject | MOF | en |
dc.subject | Calcium MOF | en |
dc.subject | Electrochemistry | en |
dc.subject | scXRD | en |
dc.subject | VTXRD | en |
dc.subject | BioMOF | en |
dc.subject | QD Chemistry | en |
dc.subject | TK Electrical engineering. Electronics Nuclear engineering | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.subject.lcc | TK | en |
dc.title | Solvothermal synthesis of a novel calcium metal-organic 2 framework : high temperature and electrochemical behaviour | en |
dc.type | Journal article | en |
dc.contributor.sponsor | European Research Council | en |
dc.contributor.sponsor | The Faraday Institution | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.3390/molecules26227048 | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | https://www.mdpi.com/1420-3049/26/22/7048 | en |
dc.identifier.grantnumber | 787073 | en |
dc.identifier.grantnumber | EP/T005602/1 | en |
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