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dc.contributor.authorMain, Russell Matthew
dc.contributor.authorCordes, David B.
dc.contributor.authorDesai, Aamod V.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWheatley, Paul
dc.contributor.authorArmstrong, A. Robert
dc.contributor.authorMorris, Russell E.
dc.identifier.citationMain , R M , Cordes , D B , Desai , A V , Slawin , A M Z , Wheatley , P , Armstrong , A R & Morris , R E 2021 , ' Solvothermal synthesis of a novel calcium metal-organic 2 framework : high temperature and electrochemical behaviour ' , Molecules , vol. 26 , no. 22 , 7048 .
dc.identifier.otherPURE: 276750118
dc.identifier.otherPURE UUID: e6dc4a7d-2625-4d35-81ec-4de0dae4b42a
dc.identifier.otherORCID: /0000-0003-1937-0936/work/103865167
dc.identifier.otherORCID: /0000-0002-9527-6418/work/103865276
dc.identifier.otherORCID: /0000-0002-5366-9168/work/103865383
dc.identifier.otherORCID: /0000-0001-7809-0315/work/103865388
dc.identifier.otherORCID: /0000-0001-7219-3428/work/103865939
dc.identifier.otherScopus: 85119973479
dc.identifier.otherWOS: 000727569800001
dc.descriptionThis research was funded by the European Research Council AdG grant number ADOR- 336 787073 and by the Faraday Institution (grant number FIRG018).en
dc.description.abstractThe rapid growth in the field of metal-organic frameworks (MOFs) over recent years has highlighted their high potential in a variety of applications. For biological and environmental applications MOFs with low toxicity are vitally important to avoid any harmful effects. For this reason, Ca-based MOFs are highly desirable owing to their low cost and high biocompatibility. Useful Ca MOFs are still rare owing to the ionic character and large size of the Ca2+ ion tending to produce dense phases. Presented here is a novel Ca-based MOF containing 2,3-dihyrdoxyterephthalate (2,3-dhtp) linkers Ca(2,3-dhtp)(H2O) (SIMOF-4). The material undergoes a phase transformation on heating, which can be followed by variable temperature powder X-ray diffraction. The structure of the high temperature form was obtained using single-crystal X-ray diffraction. The electrochemical properties of SIMOF-4 were also investigated for use in a Na ion battery.
dc.rightsCopyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://
dc.subjectCalcium MOFen
dc.subjectQD Chemistryen
dc.subjectTK Electrical engineering. Electronics Nuclear engineeringen
dc.titleSolvothermal synthesis of a novel calcium metal-organic 2 framework : high temperature and electrochemical behaviouren
dc.typeJournal articleen
dc.contributor.sponsorEuropean Research Councilen
dc.contributor.sponsorThe Faraday Institutionen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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