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An efficient synthesis of 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide (Woollins’ Reagent)

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dc.contributor.authorHua, Guoxiong
dc.contributor.authorWoollins, J Derek
dc.date.accessioned2021-11-11T10:30:11Z
dc.date.available2021-11-11T10:30:11Z
dc.date.issued2021-11-10
dc.identifier.citationHua , G & Woollins , J D 2021 , ' An efficient synthesis of 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide (Woollins’ Reagent) ' , ACS Omega , vol. Articles ASAP . https://doi.org/10.1021/acsomega.1c04753en
dc.identifier.issn2470-1343
dc.identifier.otherPURE: 276296007
dc.identifier.otherPURE UUID: e0e7ecbe-9c67-4b35-9cc5-6cd8024828b1
dc.identifier.otherORCID: /0000-0002-1498-9652/work/103137441
dc.identifier.otherScopus: 85119457058
dc.identifier.otherWOS: 000754397700037
dc.identifier.urihttps://hdl.handle.net/10023/24311
dc.descriptionAuthors are grateful to the University of St Andrews for financial support.en
dc.description.abstractAn improved approach for the preparation of 2,4-bis(phenyl)-1,3-diselena-2,4-diphosphetane-2,4-diselenide (Woollins’ reagent) is described. Reacting dichlorophenylphosphine with Na2Se which was in-situ prepared from the reaction of elemental selenium and metal sodium in the presence of naphthalene in refluxing THF generated Wooollins’ reagent with ex-cellent purity and yield of up to 96.4%.
dc.format.extent3
dc.language.isoeng
dc.relation.ispartofACS Omegaen
dc.rightsCopyright © 2021 The Authors. Published by American Chemical Society. Open Access. This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.en
dc.subjectQD Chemistryen
dc.subject3rd-DASen
dc.subject.lccQDen
dc.titleAn efficient synthesis of 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4-diselenide (Woollins’ Reagent)en
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doihttps://doi.org/10.1021/acsomega.1c04753
dc.description.statusPeer revieweden


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