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dc.contributor.authorMcRoberts, Kirsty
dc.contributor.authorZhou, Wuzong
dc.date.accessioned2021-11-02T12:30:03Z
dc.date.available2021-11-02T12:30:03Z
dc.date.issued2021-11-21
dc.identifier.citationMcRoberts , K & Zhou , W 2021 , ' Reversed crystal growth of metal organic framework MIL-68(In) ' , CrystEngComm , vol. 23 , no. 43 , pp. 7658-7662 . https://doi.org/10.1039/d1ce01120ken
dc.identifier.issn1466-8033
dc.identifier.otherPURE: 276522402
dc.identifier.otherPURE UUID: 8bcfdc2d-bdbe-4948-9ee9-d93f517ee41a
dc.identifier.otherJisc: c3eb8e3377aa4b1eb0e9db9b0a01643c
dc.identifier.otherWOS: 000709880800001
dc.identifier.otherORCID: /0000-0001-9752-7076/work/103137331
dc.identifier.otherScopus: 85118937728
dc.identifier.urihttp://hdl.handle.net/10023/24240
dc.descriptionK. McR. wishes to thank University of St Andrews for a scholarship.en
dc.description.abstractAn investigation of the crystal growth of metal organic framework MIL-68(In) under solvothermal conditions revealed a non-classical reversed crystal growth mechanism via a route of nanorods – orientated aggregation into polycrystalline microrods – surface recrystallisation into a hexagonal shell – extension of recrystallisation from the surface to the core of the microrods. Terephthalic acid molecules which are adsorbed onto the surface of nanorods are believed to strengthen the inter-particle interaction, leading to an early stage aggregation of the monocrystalline nanorods.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofCrystEngCommen
dc.rightsCopyright © TheAuthors 2021. Open Access. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.subjectFormation mechanismen
dc.subjectMorphologyen
dc.subjectZeoliteen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleReversed crystal growth of metal organic framework MIL-68(In)en
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.identifier.doihttps://doi.org/10.1039/d1ce01120k
dc.description.statusPeer revieweden


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