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Reversed crystal growth of metal organic framework MIL-68(In)
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dc.contributor.author | McRoberts, Kirsty | |
dc.contributor.author | Zhou, Wuzong | |
dc.date.accessioned | 2021-11-02T12:30:03Z | |
dc.date.available | 2021-11-02T12:30:03Z | |
dc.date.issued | 2021-11-21 | |
dc.identifier | 276522402 | |
dc.identifier | 8bcfdc2d-bdbe-4948-9ee9-d93f517ee41a | |
dc.identifier | 000709880800001 | |
dc.identifier | 85118937728 | |
dc.identifier.citation | McRoberts , K & Zhou , W 2021 , ' Reversed crystal growth of metal organic framework MIL-68(In) ' , CrystEngComm , vol. 23 , no. 43 , pp. 7658-7662 . https://doi.org/10.1039/d1ce01120k | en |
dc.identifier.issn | 1466-8033 | |
dc.identifier.other | Jisc: c3eb8e3377aa4b1eb0e9db9b0a01643c | |
dc.identifier.other | ORCID: /0000-0001-9752-7076/work/103137331 | |
dc.identifier.uri | https://hdl.handle.net/10023/24240 | |
dc.description | K. McR. wishes to thank University of St Andrews for a scholarship. | en |
dc.description.abstract | An investigation of the crystal growth of metal organic framework MIL-68(In) under solvothermal conditions revealed a non-classical reversed crystal growth mechanism via a route of nanorods – orientated aggregation into polycrystalline microrods – surface recrystallisation into a hexagonal shell – extension of recrystallisation from the surface to the core of the microrods. Terephthalic acid molecules which are adsorbed onto the surface of nanorods are believed to strengthen the inter-particle interaction, leading to an early stage aggregation of the monocrystalline nanorods. | |
dc.format.extent | 5 | |
dc.format.extent | 2425793 | |
dc.language.iso | eng | |
dc.relation.ispartof | CrystEngComm | en |
dc.subject | Formation mechanism | en |
dc.subject | Morphology | en |
dc.subject | Zeolite | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Reversed crystal growth of metal organic framework MIL-68(In) | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | 10.1039/d1ce01120k | |
dc.description.status | Peer reviewed | en |
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