Files in this item
Azetidinium lead halide Ruddlesden-Popper phases
Item metadata
dc.contributor.author | Tian, Jiyu | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.contributor.author | Morrison, Finlay D. | |
dc.date.accessioned | 2021-10-29T10:30:02Z | |
dc.date.available | 2021-10-29T10:30:02Z | |
dc.date.issued | 2021-10-27 | |
dc.identifier.citation | Tian , J , Zysman-Colman , E & Morrison , F D 2021 , ' Azetidinium lead halide Ruddlesden-Popper phases ' , Molecules , vol. 26 , no. 21 , 6474 . https://doi.org/10.3390/molecules26216474 | en |
dc.identifier.issn | 1420-3049 | |
dc.identifier.other | PURE: 276384223 | |
dc.identifier.other | PURE UUID: 0039da90-5c93-4ae5-8dbd-abd5001f9ba3 | |
dc.identifier.other | ORCID: /0000-0002-2813-3142/work/102330323 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/102330562 | |
dc.identifier.other | Scopus: 85118370902 | |
dc.identifier.other | WOS: 000806934700001 | |
dc.identifier.uri | https://hdl.handle.net/10023/24221 | |
dc.description.abstract | A family of Ruddlesden–Popper (n = 1) layered perovskite-related phases, Az2PbClxBr4−x with composition 0 ≤ x ≤ 4 were obtained using mechanosynthesis. These compounds are isostructural with K2NiF4 and therefore adopt the idealised n = 1 Ruddlesden–Popper structure. A linear variation in unit cell volume as a function of anion average radius is observed. A tunable bandgap is achieved, ranging from 2.81 to 3.43 eV, and the bandgap varies in a second-order polynomial relationship with the halide composition. | |
dc.format.extent | 8 | |
dc.language.iso | eng | |
dc.relation.ispartof | Molecules | en |
dc.rights | Copyright © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). | en |
dc.subject | Layered perovskite | en |
dc.subject | Bandgap tuning | en |
dc.subject | Azetidinium | en |
dc.subject | Ruddlesden-Popper | en |
dc.subject | Structure-property relations | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Azetidinium lead halide Ruddlesden-Popper phases | en |
dc.type | Journal article | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.3390/molecules26216474 | |
dc.description.status | Peer reviewed | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.