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dc.contributor.authorTian, Jiyu
dc.contributor.authorZysman-Colman, Eli
dc.contributor.authorMorrison, Finlay D.
dc.date.accessioned2021-10-29T10:30:02Z
dc.date.available2021-10-29T10:30:02Z
dc.date.issued2021-10-27
dc.identifier.citationTian , J , Zysman-Colman , E & Morrison , F D 2021 , ' Azetidinium lead halide Ruddlesden-Popper phases ' , Molecules , vol. 26 , no. 21 , 6474 . https://doi.org/10.3390/molecules26216474en
dc.identifier.issn1420-3049
dc.identifier.otherPURE: 276384223
dc.identifier.otherPURE UUID: 0039da90-5c93-4ae5-8dbd-abd5001f9ba3
dc.identifier.otherORCID: /0000-0002-2813-3142/work/102330323
dc.identifier.otherORCID: /0000-0001-7183-6022/work/102330562
dc.identifier.otherScopus: 85118370902
dc.identifier.otherWOS: 000806934700001
dc.identifier.urihttps://hdl.handle.net/10023/24221
dc.description.abstractA family of Ruddlesden–Popper (n = 1) layered perovskite-related phases, Az2PbClxBr4−x with composition 0 ≤ x ≤ 4 were obtained using mechanosynthesis. These compounds are isostructural with K2NiF4 and therefore adopt the idealised n = 1 Ruddlesden–Popper structure. A linear variation in unit cell volume as a function of anion average radius is observed. A tunable bandgap is achieved, ranging from 2.81 to 3.43 eV, and the bandgap varies in a second-order polynomial relationship with the halide composition.
dc.format.extent8
dc.language.isoeng
dc.relation.ispartofMoleculesen
dc.rightsCopyright © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).en
dc.subjectLayered perovskiteen
dc.subjectBandgap tuningen
dc.subjectAzetidiniumen
dc.subjectRuddlesden-Popperen
dc.subjectStructure-property relationsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleAzetidinium lead halide Ruddlesden-Popper phasesen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doihttps://doi.org/10.3390/molecules26216474
dc.description.statusPeer revieweden


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