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Activation of anion redox in P3 structure cobalt-doped sodium manganese oxide via introduction of transition metal vacancies
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dc.contributor.author | Kim, Eun Jeong | |
dc.contributor.author | Mofredj, Kenza | |
dc.contributor.author | Pickup, David | |
dc.contributor.author | Chadwick, Alan | |
dc.contributor.author | Irvine, John Thomas Sirr | |
dc.contributor.author | Armstrong, Robert | |
dc.date.accessioned | 2021-10-19T23:38:41Z | |
dc.date.available | 2021-10-19T23:38:41Z | |
dc.date.issued | 2021-01-01 | |
dc.identifier.citation | Kim , E J , Mofredj , K , Pickup , D , Chadwick , A , Irvine , J T S & Armstrong , R 2021 , ' Activation of anion redox in P3 structure cobalt-doped sodium manganese oxide via introduction of transition metal vacancies ' , Journal of Power Sources , vol. 481 , 229010 . https://doi.org/10.1016/j.jpowsour.2020.229010 | en |
dc.identifier.issn | 0378-7753 | |
dc.identifier.other | PURE: 270852816 | |
dc.identifier.other | PURE UUID: 2b8b03e8-4233-4788-9d01-67ca2067a07f | |
dc.identifier.other | ORCID: /0000-0002-8394-3359/work/82788538 | |
dc.identifier.other | ORCID: /0000-0003-1937-0936/work/82788547 | |
dc.identifier.other | Scopus: 85092900789 | |
dc.identifier.other | WOS: 000593863700005 | |
dc.identifier.uri | https://hdl.handle.net/10023/24170 | |
dc.description | EJK would like to thank the Alistore ERI for the award of a studentship. This work was supported by the Faraday Institution (grant number FIRG018). | en |
dc.description.abstract | Additional capacity delivered by oxygen redox activity may in principle represent a means of enhancing the electrochemical performance of layered sodium transition metal oxides. However, irreversible structural changes occurring during cycling typically cause significant capacity fade with limited reversibility of oxygen redox processes. Here, P3-structure Na0.67Co0.2Mn0.8O2 was synthesised under two different reaction conditions. Both materials exhibit very stable cycling performance in the voltage range 1.8-3.8 V where the redox couples of transition metals entirely dominate the electrochemical reaction. For the compound prepared under more oxidising conditions, anion redox activity is triggered in the wider voltage window 1.8-4.4 V in a reversible manner with exceptionally small voltage hysteresis (20 mV). The presence of vacancies in the transition metal layers is shown to play a critical role not only in generating unpaired O 2p states but also in stabilising the crystal structure in the high voltage region. | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of Power Sources | en |
dc.rights | Copyright © 2020 Elsevier B.V. All rights reserved. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1016/j.jpowsour.2020.229010 | en |
dc.subject | Sodium ion batteries | en |
dc.subject | Layered oxides | en |
dc.subject | Oxygen redox | en |
dc.subject | Transition metal vacancies | en |
dc.subject | P3 structure | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Activation of anion redox in P3 structure cobalt-doped sodium manganese oxide via introduction of transition metal vacancies | en |
dc.type | Journal article | en |
dc.contributor.sponsor | The Faraday Institution | en |
dc.description.version | Postprint | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Centre for Designer Quantum Materials | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1016/j.jpowsour.2020.229010 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2021-10-20 | |
dc.identifier.grantnumber | EP/T005602/1 | en |
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