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dc.contributor.authorAzad, Abul K.
dc.contributor.authorAbdalla, Abdalla M.
dc.contributor.authorAfif, Ahmed
dc.contributor.authorAzad, Atia
dc.contributor.authorAfroze, Shammya
dc.contributor.authorIdris, Azam Che
dc.contributor.authorPark, Jun-Young
dc.contributor.authorSaqib, Mohammad
dc.contributor.authorRadenahmad, Nikdalila
dc.contributor.authorHossain, Shahzad
dc.contributor.authorElius, Iftakhar Bin
dc.contributor.authorAl-Mamun, Md.
dc.contributor.authorZaini, Juliana
dc.contributor.authorAl-Hinai, Amer
dc.contributor.authorReza, Md. Sumon
dc.contributor.authorIrvine, John T. S.
dc.date.accessioned2021-10-04T09:30:10Z
dc.date.available2021-10-04T09:30:10Z
dc.date.issued2021-09-29
dc.identifier.citationAzad , A K , Abdalla , A M , Afif , A , Azad , A , Afroze , S , Idris , A C , Park , J-Y , Saqib , M , Radenahmad , N , Hossain , S , Elius , I B , Al-Mamun , M , Zaini , J , Al-Hinai , A , Reza , M S & Irvine , J T S 2021 , ' Improved mechanical strength, proton conductivity and power density in an ‘all-protonic’ ceramic fuel cell at intermediate temperature ' , Scientific Reports , vol. 11 , 19382 . https://doi.org/10.1038/s41598-021-98987-6en
dc.identifier.issn2045-2322
dc.identifier.otherPURE: 276099410
dc.identifier.otherPURE UUID: 4f71c95f-89ec-4cc9-8c61-e794a492a96e
dc.identifier.otherJisc: e26cfe1d62ff456487f58a9838309a54
dc.identifier.otherpublisher-id: s41598-021-98987-6
dc.identifier.othermanuscript: 98987
dc.identifier.otherORCID: /0000-0002-8394-3359/work/100900933
dc.identifier.otherScopus: 85116057401
dc.identifier.urihttp://hdl.handle.net/10023/24077
dc.descriptionThe authors AA and NR would like to thank Universiti Brunei Darussalam for providing a UGS scholarship to perform this research. This work was supported by the UBD CRG project: UBD/OVACRI/CRGWG(006)/161201.en
dc.description.abstractProtonic ceramic fuel cells (PCFCs) have become the most efficient, clean and cost-effective electrochemical energy conversion devices in recent years. While significant progress has been made in developing proton conducting electrolyte materials, mechanical strength and durability still need to be improved for efficient applications. We report that adding 5 mol% Zn to the Y-doped barium cerate-zirconate perovskite electrolyte material can significantly improve the sintering properties, mechanical strength, durability and performance. Using same proton conducting material in anodes, electrolytes and cathodes to make a strong structural backbone shows clear advantages in mechanical strength over other arrangements with different materials. Rietveld analysis of the X-ray and neutron diffraction data of BaCe0.7Zr0.1Y0.15Zn0.05O3−δ (BCZYZn05) revealed a pure orthorhombic structure belonging to the Pbnm space group. Structural and electrochemical analyses indicate highly dense and high proton conductivity at intermediate temperature (400–700 °C). The anode-supported single cell, NiO-BCZYZn05|BCZYZn05|BSCF-BCZYZn05, demonstrates a peak power density of 872 mW cm−2 at 700 °C which is one of the highest power density in an all-protonic solid oxide fuel cell. This observation represents an important step towards commercially viable SOFC technology.
dc.format.extent10
dc.language.isoeng
dc.relation.ispartofScientific Reportsen
dc.rightsCopyright © The Author(s) 2021. Open Access. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder.en
dc.subjectQC Physicsen
dc.subjectNDASen
dc.subject.lccQCen
dc.titleImproved mechanical strength, proton conductivity and power density in an ‘all-protonic’ ceramic fuel cell at intermediate temperatureen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.Centre for Energy Ethicsen
dc.contributor.institutionUniversity of St Andrews.Centre for Designer Quantum Materialsen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1038/s41598-021-98987-6
dc.description.statusPeer revieweden


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