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The X-ray structure of the title compound has been determined for the first time. Its molecular structure is in good agreement with those previously determined for similar benzyl halides and the angles between the ring–Cl bonds in adjacent molecules show values in good agreement with an early Zeeman quadrupole spectroscopy study.
Aitken , R A & Slawin , A M Z 2021 , ' 4-Chlorobenzyl chloride ' , Molbank , vol. 2021 , no. 3 , M1265 . https://doi.org/10.3390/M1265
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