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dc.contributor.authorHofmann, Laura Elena
dc.contributor.authorAltmann, Lisa-Marie
dc.contributor.authorFischer, Oliver
dc.contributor.authorPrusko, Lea
dc.contributor.authorXiao, Ganyuan
dc.contributor.authorWestwood, Nicholas J.
dc.contributor.authorHeinrich, Markus R.
dc.date.accessioned2021-07-27T08:30:05Z
dc.date.available2021-07-27T08:30:05Z
dc.date.issued2021-07-23
dc.identifier.citationHofmann , L E , Altmann , L-M , Fischer , O , Prusko , L , Xiao , G , Westwood , N J & Heinrich , M R 2021 , ' Cleavage of organosolv lignin to phenols using nitrogen monoxide and hydrazine ' , ACS Omega , vol. Articles ASAP . https://doi.org/10.1021/acsomega.1c00996en
dc.identifier.issn2470-1343
dc.identifier.otherPURE: 275200124
dc.identifier.otherPURE UUID: 8d28d669-4285-4897-88c8-e8b713c246cb
dc.identifier.otherRIS: urn:7C37B35F6B658801ED51EE514829C719
dc.identifier.otherORCID: /0000-0003-0630-0138/work/97884525
dc.identifier.otherScopus: 85112411634
dc.identifier.urihttp://hdl.handle.net/10023/23646
dc.descriptionFunding: The authors are grateful to the support by the Deutsche Bundesstiftung Umwelt (DBU).en
dc.description.abstractFrom the variety of methods known for the depolymerization of organosolv lignin, a broad range of diversely substituted aromatic compounds are available today. In the present work, a novel two-step reaction sequence is reported, which is focused on the formation of phenols. While the first step of the depolymerization strategy comprises the 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)-catalyzed oxidation of organosolv lignin with nitrogen monoxide so that two waste materials are combined, cleavage to the phenolic target compounds is achieved in the second step employing hydrazine and potassium hydroxide under Wolff–Kishner-type conditions. Besides the fact that the novel strategy proceeds via an untypical form of oxidized organosolv lignin, the two-step sequence is further able to provide phenols as cleavage products, which bear no substituent at the 4-position.
dc.format.extent9
dc.language.isoeng
dc.relation.ispartofACS Omegaen
dc.rightsCopyright © 2021 The Authors. Published by American Chemical Society. Open Access. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.en
dc.subjectHydrocarbonsen
dc.subjectNitrogenen
dc.subjectAromatic compoundsen
dc.subjectBiopolymersen
dc.subjectOrganic polymersen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleCleavage of organosolv lignin to phenols using nitrogen monoxide and hydrazineen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.Biomedical Sciences Research Complexen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1021/acsomega.1c00996
dc.description.statusPeer revieweden


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