Files in this item
Cleavage of organosolv lignin to phenols using nitrogen monoxide and hydrazine
Item metadata
dc.contributor.author | Hofmann, Laura Elena | |
dc.contributor.author | Altmann, Lisa-Marie | |
dc.contributor.author | Fischer, Oliver | |
dc.contributor.author | Prusko, Lea | |
dc.contributor.author | Xiao, Ganyuan | |
dc.contributor.author | Westwood, Nicholas J. | |
dc.contributor.author | Heinrich, Markus R. | |
dc.date.accessioned | 2021-07-27T08:30:05Z | |
dc.date.available | 2021-07-27T08:30:05Z | |
dc.date.issued | 2021-07-23 | |
dc.identifier | 275200124 | |
dc.identifier | 8d28d669-4285-4897-88c8-e8b713c246cb | |
dc.identifier | 85112411634 | |
dc.identifier | 000697781900007 | |
dc.identifier.citation | Hofmann , L E , Altmann , L-M , Fischer , O , Prusko , L , Xiao , G , Westwood , N J & Heinrich , M R 2021 , ' Cleavage of organosolv lignin to phenols using nitrogen monoxide and hydrazine ' , ACS Omega , vol. Articles ASAP . https://doi.org/10.1021/acsomega.1c00996 | en |
dc.identifier.issn | 2470-1343 | |
dc.identifier.other | RIS: urn:7C37B35F6B658801ED51EE514829C719 | |
dc.identifier.other | ORCID: /0000-0003-0630-0138/work/97884525 | |
dc.identifier.uri | https://hdl.handle.net/10023/23646 | |
dc.description | Funding: The authors are grateful to the support by the Deutsche Bundesstiftung Umwelt (DBU). | en |
dc.description.abstract | From the variety of methods known for the depolymerization of organosolv lignin, a broad range of diversely substituted aromatic compounds are available today. In the present work, a novel two-step reaction sequence is reported, which is focused on the formation of phenols. While the first step of the depolymerization strategy comprises the 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)-catalyzed oxidation of organosolv lignin with nitrogen monoxide so that two waste materials are combined, cleavage to the phenolic target compounds is achieved in the second step employing hydrazine and potassium hydroxide under Wolff–Kishner-type conditions. Besides the fact that the novel strategy proceeds via an untypical form of oxidized organosolv lignin, the two-step sequence is further able to provide phenols as cleavage products, which bear no substituent at the 4-position. | |
dc.format.extent | 9 | |
dc.format.extent | 2052725 | |
dc.language.iso | eng | |
dc.relation.ispartof | ACS Omega | en |
dc.subject | Hydrocarbons | en |
dc.subject | Nitrogen | en |
dc.subject | Aromatic compounds | en |
dc.subject | Biopolymers | en |
dc.subject | Organic polymers | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Cleavage of organosolv lignin to phenols using nitrogen monoxide and hydrazine | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Biomedical Sciences Research Complex | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1021/acsomega.1c00996 | |
dc.description.status | Peer reviewed | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.