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Cleavage of organosolv lignin to phenols using nitrogen monoxide and hydrazine
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dc.contributor.author | Hofmann, Laura Elena | |
dc.contributor.author | Altmann, Lisa-Marie | |
dc.contributor.author | Fischer, Oliver | |
dc.contributor.author | Prusko, Lea | |
dc.contributor.author | Xiao, Ganyuan | |
dc.contributor.author | Westwood, Nicholas J. | |
dc.contributor.author | Heinrich, Markus R. | |
dc.date.accessioned | 2021-07-27T08:30:05Z | |
dc.date.available | 2021-07-27T08:30:05Z | |
dc.date.issued | 2021-07-23 | |
dc.identifier.citation | Hofmann , L E , Altmann , L-M , Fischer , O , Prusko , L , Xiao , G , Westwood , N J & Heinrich , M R 2021 , ' Cleavage of organosolv lignin to phenols using nitrogen monoxide and hydrazine ' , ACS Omega , vol. Articles ASAP . https://doi.org/10.1021/acsomega.1c00996 | en |
dc.identifier.issn | 2470-1343 | |
dc.identifier.other | PURE: 275200124 | |
dc.identifier.other | PURE UUID: 8d28d669-4285-4897-88c8-e8b713c246cb | |
dc.identifier.other | RIS: urn:7C37B35F6B658801ED51EE514829C719 | |
dc.identifier.other | ORCID: /0000-0003-0630-0138/work/97884525 | |
dc.identifier.other | Scopus: 85112411634 | |
dc.identifier.other | WOS: 000697781900007 | |
dc.identifier.uri | https://hdl.handle.net/10023/23646 | |
dc.description | Funding: The authors are grateful to the support by the Deutsche Bundesstiftung Umwelt (DBU). | en |
dc.description.abstract | From the variety of methods known for the depolymerization of organosolv lignin, a broad range of diversely substituted aromatic compounds are available today. In the present work, a novel two-step reaction sequence is reported, which is focused on the formation of phenols. While the first step of the depolymerization strategy comprises the 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ)-catalyzed oxidation of organosolv lignin with nitrogen monoxide so that two waste materials are combined, cleavage to the phenolic target compounds is achieved in the second step employing hydrazine and potassium hydroxide under Wolff–Kishner-type conditions. Besides the fact that the novel strategy proceeds via an untypical form of oxidized organosolv lignin, the two-step sequence is further able to provide phenols as cleavage products, which bear no substituent at the 4-position. | |
dc.format.extent | 9 | |
dc.language.iso | eng | |
dc.relation.ispartof | ACS Omega | en |
dc.rights | Copyright © 2021 The Authors. Published by American Chemical Society. Open Access. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/. | en |
dc.subject | Hydrocarbons | en |
dc.subject | Nitrogen | en |
dc.subject | Aromatic compounds | en |
dc.subject | Biopolymers | en |
dc.subject | Organic polymers | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Cleavage of organosolv lignin to phenols using nitrogen monoxide and hydrazine | en |
dc.type | Journal article | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Biomedical Sciences Research Complex | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1021/acsomega.1c00996 | |
dc.description.status | Peer reviewed | en |
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