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dc.contributor.authorMcDonald, Calum
dc.contributor.authorNi, Chengsheng
dc.contributor.authorŠvrček, Vladimir
dc.contributor.authorMacias-Montero, Manuel
dc.contributor.authorVelusamy, Tamilselvan
dc.contributor.authorConnor, Paul A.
dc.contributor.authorMaguire, Paul
dc.contributor.authorIrvine, John T. S.
dc.contributor.authorMariotti, Davide
dc.identifier.citationMcDonald , C , Ni , C , Švrček , V , Macias-Montero , M , Velusamy , T , Connor , P A , Maguire , P , Irvine , J T S & Mariotti , D 2021 , ' Carrier extraction from metallic perovskite oxide nanoparticles ' , Nanoscale , vol. Advance Article .
dc.identifier.otherRIS: urn:D92264F611CCFF0F832F22D9C0876DB1
dc.identifier.otherORCID: /0000-0002-8394-3359/work/97473047
dc.identifier.otherORCID: /0000-0002-1492-7590/work/97473392
dc.descriptionThis work was supported by EPSRC (EP/K022237/1, EP/M024938/1 and EP/R023638/1), the EPSRC Supergen SuperSolar Hub, the Department for Employment and Learning (DEL) of Northern Ireland Studentship, and by the New Energy and Industrial Technology Development Organization (NEDO).en
dc.description.abstractWe observe the extraction of carriers excited between two types of bands in the perovskite oxide, Sr-deficient strontium niobate (Sr0.9NbO3). Sr0.9NbO3 exhibits metallic behaviour and high conductivity, whilst also displaying broad absorption across the ultraviolet, visible, and near-infrared spectral regions, making it an attractive material for solar energy conversion. Furthermore, the optoelectronic properties of strontium niobate can easily be tuned by varying the Sr fraction or through doping. Sr-deficient strontium niobate exhibits a split conduction band, which enables two types of optical transitions: intraband and interband. However, whether such carriers can be extracted from an unusual material as such remains unproven. In this report, we have overcome the immense challenge of photocarrier extraction by fabricating an extremely thin absorber layer of Sr0.9NbO3 nanoparticles. These findings open up great opportunities to harvest a very broad solar spectral absorption range with reduced recombination losses.
dc.subjectQD Chemistryen
dc.titleCarrier extraction from metallic perovskite oxide nanoparticlesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. St Andrews Sustainability Instituteen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Centre for Energy Ethicsen
dc.contributor.institutionUniversity of St Andrews. Centre for Designer Quantum Materialsen
dc.description.statusPeer revieweden

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