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dc.contributor.authorTerracina, Angela
dc.contributor.authorMcHugh, Lauren N.
dc.contributor.authorMazaj, Matjaz
dc.contributor.authorVrtovec, Nika
dc.contributor.authorAgnello, Simonpietro
dc.contributor.authorCannas, Marco
dc.contributor.authorGelardi, Franco
dc.contributor.authorMorris, Russell E.
dc.contributor.authorBuscarino, Gianpiero
dc.date.accessioned2021-06-29T10:30:03Z
dc.date.available2021-06-29T10:30:03Z
dc.date.issued2021-06-22
dc.identifier.citationTerracina , A , McHugh , L N , Mazaj , M , Vrtovec , N , Agnello , S , Cannas , M , Gelardi , F , Morris , R E & Buscarino , G 2021 , ' Structure effects induced by high mechanical compaction of STAM-17-OEt MOF powders ' , European Journal of Inorganic Chemistry , vol. 2021 , no. 24 , pp. 2334-2342 . https://doi.org/10.1002/ejic.202100137en
dc.identifier.issn1434-1948
dc.identifier.otherPURE: 274375085
dc.identifier.otherPURE UUID: 6698f521-e8c2-4aae-bd97-e78b63f238bc
dc.identifier.otherRIS: urn:E0F573E33AFE1B53669D38FD263EFD44
dc.identifier.otherORCID: /0000-0001-7809-0315/work/96489436
dc.identifier.otherWOS: 000661503600001
dc.identifier.otherScopus: 85107858847
dc.identifier.urihttp://hdl.handle.net/10023/23439
dc.descriptionFinancial support by PJ-RIC-FFABR_2017 and the EPSRC grant EPSRC industrial CASE award (grant EP/N50936X/1) are acknowledged. The research programme Nanoporous materials (P1-0021) financially supported by Slovenian Research Agency (ARRS) is acknowledged as well.en
dc.description.abstractMetal-organic frameworks (MOFs) are promising materials for many potential applications, spacing from gas storage to catalysis. However, the powder form of which they are generally made is not suitable, mainly because of the low packing density. Powder compaction is therefore necessary, but also challenging because of their typical mechanical fragility. Indeed, generally, they undergo irreversibly damages upon densification processes, for example partially or totally loosing microporosity and catalytic activity. In this work, we deeply study the compaction effects on the flexible Cu(II)-based MOF STAM-17-OEt  (Cu(C10O5H8)1.6 H2O), whose chemical composition is close to that of HKUST-1, obtaining that it is, by contrast, extremely suitable for mechanical compaction processes with pressures up to 200 MPa, which increase its packing density, its catalytic activity, and preserve porosity, flexibility and water stability, characteristics of STAM-17-OEt. The results are supported by many experimental techniques including EPR spectroscopy, PXRD diffraction, CO2 isotherms studies and catalytic tests.
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen
dc.rightsCopyright © 2021 The Authors. European Journal of Inorganic Chemistry published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.en
dc.subjectEPR spectroscopyen
dc.subjectFlexible MOFsen
dc.subjectMetal-organic frameworksen
dc.subjectMOF Tabletingen
dc.subjectMOF stabilityen
dc.subjectQD Chemistryen
dc.subject3rd-DASen
dc.subject.lccQDen
dc.titleStructure effects induced by high mechanical compaction of STAM-17-OEt MOF powdersen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/ejic.202100137
dc.description.statusPeer revieweden
dc.identifier.urlhttps://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202100137#support-information-sectionen


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