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dc.contributor.authorVeselý, Ondřej
dc.contributor.authorEliášová, Pavla
dc.contributor.authorMorris, Russell E.
dc.contributor.authorČejka, Jiří
dc.date.accessioned2021-04-27T11:30:11Z
dc.date.available2021-04-27T11:30:11Z
dc.date.issued2021-04-02
dc.identifier.citationVeselý , O , Eliášová , P , Morris , R E & Čejka , J 2021 , ' Reverse ADOR : reconstruction of UTL zeolite from layered IPC-1P ' , Materials Advances , vol. Advance Article . https://doi.org/10.1039/d1ma00212ken
dc.identifier.issn2633-5409
dc.identifier.otherPURE: 273967873
dc.identifier.otherPURE UUID: b9a172e0-2e82-4704-b754-0fa85c167b89
dc.identifier.otherJisc: 79562aa45b494b43bd10a64f8981062b
dc.identifier.otherORCID: /0000-0001-7809-0315/work/93161369
dc.identifier.otherWOS: 000640275800001
dc.identifier.urihttp://hdl.handle.net/10023/23089
dc.descriptionThe authors acknowledge the support of the Czech Science Foundation to the project EXPRO (19-27551X) and OP VVV “Excellent Research Teams”, project no. CZ.02.1.01/0.0/0.0/15_003/0000417 – CUCAM. REM thanks the European Research Council for the provision of an Advanced Grant (ADOR – 787073).en
dc.description.abstractThe assembly–disassembly–organisation–reassembly (ADOR) process has led to the discovery of numerous zeolite structures, albeit limited to materials with decreased pore size in relation to the parent germanosilicate zeolite. This limitation stems from the rapid decrease in d-spacing upon hydrolysis (disassembly). Nevertheless, we have artificially increased the d-spacing of layered IPC-1P by intercalating organic species. Furthermore, we have reconstructed double four rings (D4R) between layers, thus transforming IPC-1P back into the parent UTL zeolite. This reconstruction has provided not only germanosilicate but also a new, high-silica UTL zeolite (Si/Ge = 481). Therefore, our “reverse ADOR” opens up new synthetic routes towards promising extra-large-pore zeolite-based materials with new chemical compositions.
dc.language.isoeng
dc.relation.ispartofMaterials Advancesen
dc.rightsCopyright © 2021 The Author(s). Open Access. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleReverse ADOR : reconstruction of UTL zeolite from layered IPC-1Pen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/d1ma00212k
dc.description.statusPeer revieweden


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