Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines
Abstract
Herein we report the selective hydrogenation of cyclic imides to diols and amines, homogeneously catalyzed for the first time by a complex of an earth-abundant metal, a manganese pincer complex. A plausible catalytic cycle is proposed based on informative mechanistic experiments.
Citation
Das , U K , Janes , T , Kumar , A & Milstein , D 2020 , ' Manganese catalyzed selective hydrogenation of cyclic imides to diols and amines ' , Green Chemistry , vol. 22 , no. 10 , pp. 3079-3082 . https://doi.org/10.1039/D0GC00570C
Publication
Green Chemistry
Status
Peer reviewed
ISSN
1463-9262Type
Journal article
Rights
Copyright © 2020 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/D0GC00570C
Description
U. K. D. is thankful to Govt. of India for the DST SERB Overseas Postdoctoral Fellowship. T. J. thanks the Azrieli Foundation for a postdoctoral fellowship and A.K. thanks the Planning and Budgeting Committee (PBC) for a postdoctoral fellowship. D.M. is the Israel Matz Professorial Chair of Organic Chemistry.Collections
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.