Isolation of 5′-O-sulfamyladenosine and related 3′-O-β-glucosylated adenosines from the nucleocidin producer Streptomyces calvus
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The isolation of three adenosine based metabolites 6–8 from Streptomyces calvus is reported. The metabolites are structurally related to the fluorine containing antibiotic nucleocidin 1 and two recently identified glycosylated fluoroadenosines 2 and 3, however in this case the three metabolites do not contain a fluorine, suggesting that the biosynthetic enzymes to the fluorometabolites also process their non-fluorinated counterparts.
Feng , X , Bello , D & O'Hagan , D 2021 , ' Isolation of 5′- O -sulfamyladenosine and related 3′- O -β-glucosylated adenosines from the nucleocidin producer Streptomyces calvus ' , RSC Advances , vol. 11 , no. 10 , pp. 5291-5294 . https://doi.org/10.1039/D1RA00235J
Copyright © 2021 The Author(s). Open Access article. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
DescriptionFunding: We thank EPSRC (EP/R013799/1) for a grant (DB) and the University of St Andrews for a Studentship (XF).
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