Files in this item
Reactivity of nickel metal precursors towards amido linked N-heterocyclic carbenes and their catalytic studies for cross coupling reactions
Item metadata
dc.contributor.author | Nagar, Suryakant | |
dc.contributor.author | Chatterjee, Sucheta | |
dc.contributor.author | Goswami, Dibakar | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, A.M.Z. | |
dc.contributor.author | Chauhan, Rohit Singh | |
dc.contributor.author | Prabhu, Pradnya | |
dc.date.accessioned | 2021-01-18T00:36:29Z | |
dc.date.available | 2021-01-18T00:36:29Z | |
dc.date.issued | 2020-05-01 | |
dc.identifier | 266096985 | |
dc.identifier | a90eb134-a002-4fdf-8e0d-121effd8da45 | |
dc.identifier | 85078149280 | |
dc.identifier | 000514816900017 | |
dc.identifier.citation | Nagar , S , Chatterjee , S , Goswami , D , Cordes , D B , Slawin , A M Z , Chauhan , R S & Prabhu , P 2020 , ' Reactivity of nickel metal precursors towards amido linked N -heterocyclic carbenes and their catalytic studies for cross coupling reactions ' , Inorganica Chimica Acta , vol. 504 , 119446 . https://doi.org/10.1016/j.ica.2020.119446 | en |
dc.identifier.issn | 0020-1693 | |
dc.identifier.other | RIS: urn:18585AEEACB52FD95796334C85C76B38 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/68281331 | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/68281388 | |
dc.identifier.uri | https://hdl.handle.net/10023/21278 | |
dc.description | One of the authors (RSC) is grateful to DST for the financial support under the DST young scientist scheme YSS/2014/000797. | en |
dc.description.abstract | The refluxing of chloroacetamide derivatives with n-butyl imidazole resulted in their corresponding salt of composition 1-(n-butyl)-3-N-(2-Ar)acetamido-1, 3-imidazolium chloride (Ar = furylmethyl (1a); phenylmethyl (1b)). The latter salt on treatment with DBU followed by the addition of chalcogen atom resulted into a compound [(1-(n-butyl)-3-N-(2-Ar)acetamido-1,3-imidazol-3-ylidine)E] (Ar = furylmethyl; E = S (2a); Ar = phenylmthyl; E = Se (2b)). Similarly, the reaction of the imidazolium salts with, excess K2CO3 and NiCl2·6H2O yielded compounds [(1-(n-butyl)-3-N-(2-Ar)acetamido-1,3-imidazol-3-ylidine)]2Ni (Ar = furylmethyl (3a); phenylmethyl (3b)). The latter complexes have also been isolated by using Ni(II) phosphine precursors [NiCl2(PP)] (PP = PPh3, dppf). The molecular structure of [(1-(n-butyl)-3-N-(2-furylmethyl)acetamido-1, 3-imidazol-3-ylidine)]2Ni and [(1-(n-butyl)-3-N-(2-phenylmethyl)acetamido-1, 3-imidazol-3-ylidine)]2Ni were established by single crystal X-ray diffraction analysis. The catalytic property of complex 3a and 3b for cross coupling reactions has been studied. | |
dc.format.extent | 494996 | |
dc.language.iso | eng | |
dc.relation.ispartof | Inorganica Chimica Acta | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Reactivity of nickel metal precursors towards amido linked N-heterocyclic carbenes and their catalytic studies for cross coupling reactions | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1016/j.ica.2020.119446 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2021-01-18 |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.