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Two N-{[4-(3-aryl-4-sydnonylideneamino)-5-sulfanylidene-1H-1,2,4-triazol-3-yl]methyl}benzamides as disordered ethanol monosolvates
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dc.contributor.author | Harish Chinthal, Chayanna | |
dc.contributor.author | Yathirajan, Hemmige S | |
dc.contributor.author | Kadambar, Anish Kumar | |
dc.contributor.author | Kalluraya, Balakrishna | |
dc.contributor.author | Foro, Sabine | |
dc.contributor.author | Glidewell, Christopher | |
dc.date.accessioned | 2020-11-19T10:30:14Z | |
dc.date.available | 2020-11-19T10:30:14Z | |
dc.date.issued | 2020-07 | |
dc.identifier | 271287201 | |
dc.identifier | b609cbed-c011-42d1-90be-0bf5e92ab69a | |
dc.identifier | 32695452 | |
dc.identifier | 85091707241 | |
dc.identifier | 000547498800016 | |
dc.identifier.citation | Harish Chinthal , C , Yathirajan , H S , Kadambar , A K , Kalluraya , B , Foro , S & Glidewell , C 2020 , ' Two N -{[4-(3-aryl-4-sydnonylideneamino)-5-sulfanylidene-1 H -1,2,4-triazol-3-yl]methyl}benzamides as disordered ethanol monosolvates ' , Acta Crystallographica Section E Crystallographic Communications , vol. 76 , no. Part 7 , pp. 1057-1061 . https://doi.org/10.1107/S2056989020007483 | en |
dc.identifier.issn | 2056-9890 | |
dc.identifier.other | Jisc: 15f3a9c603324974b11f3f5ebf578a2f | |
dc.identifier.other | pii: wm5563 | |
dc.identifier.other | pmc: PMC7336802 | |
dc.identifier.uri | https://hdl.handle.net/10023/21012 | |
dc.description | AKK thanks the Department of Science and Technology, Government of India, for providing a Senior Research Fellowship under the DST–INSPIRE Scheme. HSY thanks the University Grants Commission, New Delhi, for the award of a BSR Faculty Fellowship for three years. | en |
dc.description.abstract | Two new N-{[4-(3-aryl-4-sydnonylideneamino)-5-sulfanylidene-1H-1,2,4-triazol-3-yl]methyl}benzamides have been prepared by acid-promoted condensation reactions between 3-aryl-4-formylsydnones and N-[(4-amino-5-sulfanylidene-1H-1,2,4-triazol-3-yl)methyl]benzamide, and both have been crystallized as ethanol monosolvates. N-{[4-(3-Phenyl-4-sydnonylideneamino)-5-sulfanylidene-1H-1,2,4-triazol-3-yl]methyl}benzamide ethanol monosolvate, C19H15N7O3S·C2H6O ( I ), and N-({4-[3-(4-methylphenyl)-4-sydnonylideneamino]-5-sulfanylidene-1H-1,2,4-triazol-3-yl}methyl)benzamide ethanol monosolvate, C20H17N7O3S·C2H6O ( II ), differ only in the presence of a methyl group for ( II ) instead of a hydrogen atom for ( I ), and in both of them the ethanol component is disordered over two sets of atomic sites having occupancies of 0.836 (6) and 0.164 (6) in ( I ), and 0.906 (6) and 0.094 (6) in ( II ). Combinations of O—H⋯O and N—H⋯O hydrogen bonds link the molecules into cyclic, centrosymmetric four-molecule aggregates. Comparisons are made with the structures of some related compounds. | |
dc.format.extent | 18 | |
dc.format.extent | 902457 | |
dc.language.iso | eng | |
dc.relation.ispartof | Acta Crystallographica Section E Crystallographic Communications | en |
dc.subject | 1,2,4-triazoles | en |
dc.subject | crystal structure | en |
dc.subject | Disorder | en |
dc.subject | Heterocyclic compounds | en |
dc.subject | Hydrogen bonding | en |
dc.subject | Supramolecular assembly | en |
dc.subject | Sydnones | en |
dc.subject | Synthesis | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Two N-{[4-(3-aryl-4-sydnonylideneamino)-5-sulfanylidene-1H-1,2,4-triazol-3-yl]methyl}benzamides as disordered ethanol monosolvates | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.1107/S2056989020007483 | |
dc.description.status | Peer reviewed | en |
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