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Electrochemical studies of solid solution electrodes
Item metadata
dc.contributor.advisor | Vincent, Colin Angus | |
dc.contributor.author | Smith, Michael J. | |
dc.coverage.spatial | v, 173 p. | en_US |
dc.date.accessioned | 2020-11-13T17:24:50Z | |
dc.date.available | 2020-11-13T17:24:50Z | |
dc.date.issued | 1983 | |
dc.identifier.uri | https://hdl.handle.net/10023/20976 | |
dc.description.abstract | Using a method based on the analysis of the voltage transient recorded during the application of a galvanostatic pulse to a solid state, three electrode cell, diffusion coefficients of silver electro-active species in AgₓTiS₁.₈ and AgₓNbS₂ were obtained. The activation energy of the diffusion process was found to be approximately 30 kJ mole⁻¹ for TiS₁.₈ and between 34 kJ mole⁻¹ and 24 kJ mole⁻¹, decreasing with increasing guest concentration, for NbS₂. Non-linearity at extended times in the experimental timescale was ascribed to finite length effects, variation of the thermodynamic enhancement factor during the pulse, or a combination of these influences. Temperature and composition variation of the cell emf, for AgₓTiS₁.₈ and AgₓNbS₂ systems, permitted thermodynamic parameters and the compositional variation of the enhancement factors to be obtained. Investigation of the effect of the temperature of oven pre-treatment on compressed powder samples of a lithium ion conducting vitreous electrolyte on the bulk conductivity was carried out using a scanning electron microscope and ac conductivity measurements. Electronic conductivity measurements, using Wagner's method were undertaken on samples of iodotungstate and iodoarsenate glass with a view to confirmation of the low levels necessary for the use of these electrolytes in galvanic cells. | en_US |
dc.language.iso | en | en_US |
dc.publisher | University of St Andrews | |
dc.subject.lcc | QD571.S6 | |
dc.subject.lcc | ||
dc.title | Electrochemical studies of solid solution electrodes | en_US |
dc.type | Thesis | en_US |
dc.contributor.sponsor | University of St Andrews | en_US |
dc.type.qualificationlevel | Doctoral | en_US |
dc.type.qualificationname | PhD Doctor of Philosophy | en_US |
dc.publisher.institution | The University of St Andrews | en_US |
dc.identifier.doi | https://doi.org/10.17630/sta/5 |
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