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dc.contributor.authorHan, Ceng
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorLightfoot, Philip
dc.date.accessioned2020-10-13T15:30:03Z
dc.date.available2020-10-13T15:30:03Z
dc.date.issued2020-10-13
dc.identifier.citationHan , C , Cordes , D B , Slawin , A M Z & Lightfoot , P 2020 , ' Structural variations in manganese halide chain compounds mediated by methylimidazolium isomers ' , Crystals , vol. 10 , no. 10 , 930 . https://doi.org/10.3390/cryst10100930en
dc.identifier.issn2073-4352
dc.identifier.otherPURE: 270683529
dc.identifier.otherPURE UUID: c0857a13-f897-487f-a8d4-50709019029b
dc.identifier.otherORCID: /0000-0001-7048-3982/work/82179213
dc.identifier.otherORCID: /0000-0002-9527-6418/work/82179248
dc.identifier.otherORCID: /0000-0002-5366-9168/work/82179408
dc.identifier.otherScopus: 85092515786
dc.identifier.otherWOS: 000584466900001
dc.identifier.urihttps://hdl.handle.net/10023/20774
dc.descriptionThis research was funded by the China Scholarship Council (studentship to CH), grant number “201806050003” the University of St Andrews.en
dc.description.abstractThe structures of two new hybrid organic–inorganic manganese halide compounds [1MiH]MnCl3(H2O) and [4MiH]MnCl3(H2O) ([1MiH] = 1-methylimidazolium, [4MiH] = 4-methylimidazolium) have been determined by single crystal X-ray diffraction. Both are composed of one dimensional [MnCl3(H2O)]n− edge-sharing octahedral chains. The structures are compared to the previously reported isomeric analogue [2MiH]MnCl3(H2O) ([2MiH] = 2-methylimidazolium), and three closely related compounds. The variations in packing of the inorganic chains are shown to be influenced by hydrogen bonding abilities of the imidazolium or related moieties. Both new compounds show intense red luminescence at ambient temperature under UV irradiation.
dc.format.extent10
dc.language.isoeng
dc.relation.ispartofCrystalsen
dc.rightsCopyright © 2020 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).en
dc.subjectCrystal structureen
dc.subjectManganese halidesen
dc.subjectOne dimensionalen
dc.subjectRed luminescenceen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleStructural variations in manganese halide chain compounds mediated by methylimidazolium isomersen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.3390/cryst10100930
dc.description.statusPeer revieweden


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