A facile synthesis of Robinson’s NHC-stabilised diborane(4)

Trose, Michael; Cordes, David B.; Slawin, Alexandra M. Z.; Stasch, Andreas

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dc.contributor.author	Trose, Michael
dc.contributor.author	Cordes, David B.
dc.contributor.author	Slawin, Alexandra M. Z.
dc.contributor.author	Stasch, Andreas
dc.date.accessioned	2020-07-23T11:30:05Z
dc.date.available	2020-07-23T11:30:05Z
dc.date.issued	2020-10-27
dc.identifier	268938529
dc.identifier	4f2003cf-9a3a-49b6-bb51-478a5697db6f
dc.identifier	000551134600001
dc.identifier	85088314193
dc.identifier.citation	Trose , M , Cordes , D B , Slawin , A M Z & Stasch , A 2020 , ' A facile synthesis of Robinson’s NHC-stabilised diborane(4) ' , European Journal of Inorganic Chemistry , vol. 2020 , no. 40 , pp. 3811-3814 . https://doi.org/10.1002/ejic.202000596	en
dc.identifier.issn	1434-1948
dc.identifier.other	ORCID: /0000-0002-9527-6418/work/77893655
dc.identifier.other	ORCID: /0000-0002-5366-9168/work/77893668
dc.identifier.other	ORCID: /0000-0002-7407-8287/work/77893789
dc.identifier.uri	https://hdl.handle.net/10023/20318
dc.description.abstract	Reactions of bis(pinacolato)diboron (B2pin2) with [(IDip)AlH3] (IDip = (HCNDip)2C:, Dip = 2,6-iPr2C6H3) afforded both the new diborane [(IDip)BH2B(pin)] and the known compound [(IDip)BH2BH2(IDip)] in a facile one-pot procedure; the latter reaction is improved by the addition of free IDip. [(IDip)AlH3] transfers both IDip and hydride ligands to the diborane moiety in a halide-free approach. [(IDip)BH2B(pin)] was structurally and spectroscopically characterised and additional spectroscopic data for [(IDip)BH2BH2(IDip)] is reported.
dc.format.extent	5
dc.format.extent	684067
dc.language.iso	eng
dc.relation.ispartof	European Journal of Inorganic Chemistry	en
dc.subject	Aluminium	en
dc.subject	Diboranes	en
dc.subject	Group 13 elements	en
dc.subject	Hydrides	en
dc.subject	N-heterocyclic carbenes	en
dc.subject	QD Chemistry	en
dc.subject	DAS	en
dc.subject.lcc	QD	en
dc.title	A facile synthesis of Robinson’s NHC-stabilised diborane(4)	en
dc.type	Journal article	en
dc.contributor.institution	University of St Andrews. School of Chemistry	en
dc.contributor.institution	University of St Andrews. EaSTCHEM	en
dc.identifier.doi	10.1002/ejic.202000596
dc.description.status	Peer reviewed	en

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University of St Andrews Research

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