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dc.contributor.authorWarke, Matthew R.
dc.contributor.authorEdwards, Nicholas P.
dc.contributor.authorWogelius, Roy A.
dc.contributor.authorManning, Phillip L.
dc.contributor.authorBergmann, Uwe
dc.contributor.authorEgerton, Victoria M.
dc.contributor.authorKimball, Katalina C.
dc.contributor.authorGarwood, Russell J.
dc.contributor.authorBeukes, Nicolas J.
dc.contributor.authorSchröder, Stefan
dc.identifier.citationWarke , M R , Edwards , N P , Wogelius , R A , Manning , P L , Bergmann , U , Egerton , V M , Kimball , K C , Garwood , R J , Beukes , N J & Schröder , S 2019 , ' Decimeter-scale mapping of carbonate-controlled trace element distribution in Neoarchean cuspate stromatolites ' , Geochimica et Cosmochimica Acta , vol. 261 .
dc.identifier.otherPURE: 259622599
dc.identifier.otherPURE UUID: 9bf78f5e-7632-4e1e-b1f8-85e449281d04
dc.identifier.otherRIS: urn:90F31FB5402EAB477E23BF2E9B02BB6B
dc.identifier.otherORCID: /0000-0001-9830-0383/work/59698769
dc.identifier.otherWOS: 000478786500004
dc.identifier.otherScopus: 85069546590
dc.descriptionMRW was funded by a NERC PhD studentship at the University of Manchester. PLM thanks STFC for their support (ST/M001814/1). We are grateful to SSRL for continued support for imaging at beamline 6-2 at SLAC. We are also grateful to the Manchester X-Ray Imaging Facility, which was funded in part by the EPSRC (grants EP/F007906/1, EP/F001452/1 and EP/I02249X/1).en
dc.description.abstractAncient stromatolites can provide key insights into the early evolution of life on Earth. Neoarchean fenestrate stromatolites from the ∼2520 Ma Upper Nauga Formation (Transvaal Supergroup, South Africa) preserve cuspate morphologies. They possess clearly delineated support and drape structures interpreted as dolomitized microbial mat material. Petrographic observations show that the biogenic structures are composed of planar-s to non-planar ferroan dolomite, encased in ferroan calcite, including herringbone calcite textures. The cuspate stromatolites were analyzed using Synchrotron Rapid Scanning X-Ray Fluorescence (SRS-XRF) and more conventional techniques to determine: (i) whether element distributions could be distinguished in ancient stromatolites at both cm to dm scales, (ii) whether element distributions show variation between biogenic and abiogenic textures, and (iii) the sample’s paragenesis. The distributions of Ca, Fe, Mn, Pb, Cu, As, Br, Al, Si, P, and S directly correspond to dolomitized stromatolitic structures and show trace element distributions are principally controlled by calcite and dolomite occurrence. Dolomite formation was mainly driven by seawater-derived fluids given the high concentrations of Fe and retention of marine shale-normalized rare earth element and yttrium (REYSN) patterns, however the spatial association of dolomite to stromatolite structures may reflect microbially-influenced mineral nucleation. Given the complexity of this sample’s paragenetic evolution, trace metal distributions cannot be conclusively tied to specific metabolic pathways, bioaccumulation or passive binding, however, the results show SRS-XRF can be used for quantifiable, spatial, in-situ investigation of ancient microbialites.
dc.relation.ispartofGeochimica et Cosmochimica Actaen
dc.rightsCopyright © 2019 Published by Elsevier Ltd. This work is made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at
dc.subjectX-ray fluorescenceen
dc.subjectNauga formationen
dc.subjectGE Environmental Sciencesen
dc.subjectSDG 14 - Life Below Wateren
dc.titleDecimeter-scale mapping of carbonate-controlled trace element distribution in Neoarchean cuspate stromatolitesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Earth & Environmental Sciencesen
dc.description.statusPeer revieweden

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