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dc.contributor.authorBidal, Yannick D.
dc.contributor.authorUrbina-Blanco, César A.
dc.contributor.authorPoater, Albert
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorCavallo, Luigi
dc.contributor.authorCazin, Catherine S. J.
dc.date.accessioned2020-07-04T23:42:06Z
dc.date.available2020-07-04T23:42:06Z
dc.date.issued2019-08-14
dc.identifier.citationBidal , Y D , Urbina-Blanco , C A , Poater , A , Cordes , D B , Slawin , A M Z , Cavallo , L & Cazin , C S J 2019 , ' Electronic effects in mixed N-heterocyclic carbene/phosphite indenylidene ruthenium metathesis catalysts ' , Dalton Transactions , vol. 48 , no. 30 , pp. 11326-11337 . https://doi.org/10.1039/C9DT01811Een
dc.identifier.issn1477-9226
dc.identifier.otherPURE: 260598328
dc.identifier.otherPURE UUID: d6434eff-9aa4-4f9d-8cd5-60c98109a339
dc.identifier.otherBibtex: urn:c62f4c6813cfea0fcdb9d7ac36236178
dc.identifier.otherORCID: /0000-0002-9527-6418/work/60630652
dc.identifier.otherORCID: /0000-0002-5366-9168/work/60630657
dc.identifier.otherWOS: 000477957200015
dc.identifier.otherScopus: 85070095804
dc.identifier.urihttp://hdl.handle.net/10023/20208
dc.descriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to CSJC), the EC (CP-FP 211468-2 EUMET and CIG09-GA-2011-293900) and the MICINN (PGC2018-097722-B-I00 to AP) for funding.en
dc.description.abstractFive new complexes [RuCl2(SIMes)(Ind)(O-pXC5H4)] bearing different para-substituted triphenylphosphites (X = H, OCH3, CF3, Cl, SF5 and CN) were synthesised and used to study the effect of the electronic properties of the phosphite on olefin metathesis activity. Investigations of the physical properties of the new ligands and complexes were performed using physicochemical and DFT calculations. The catalytic activity of the complexes was benchmarked in challenging ring closing metathesis transformations featuring the formation of tetra-substituted double bonds. Complex [RuCl2(SIMes)(Ind)P(O-pCF3C5H4)3] (3c) exhibited a particularly high catalytic activity, superior to state-of-the-art catalysts, and was further tested on a wide range of substrates.
dc.format.extent12
dc.language.isoeng
dc.relation.ispartofDalton Transactionsen
dc.rightsCopyright © 2019 The Author(s). This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the author created accepted manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C9DT01811Een
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleElectronic effects in mixed N-heterocyclic carbene/phosphite indenylidene ruthenium metathesis catalystsen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C9DT01811E
dc.description.statusPeer revieweden
dc.date.embargoedUntil2020-07-05


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