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Three 4-(4-fluorophenyl)piperazin-1-ium salts containing organic anions : supramolecular assembly in one, two and three dimensions
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dc.contributor.author | Chinthal, Chayanna Harish | |
dc.contributor.author | Yathirajan, Hemmige S. | |
dc.contributor.author | Archana, Sreeramapura D. | |
dc.contributor.author | Foro, Sabine | |
dc.contributor.author | Glidewell, Christopher | |
dc.date.accessioned | 2020-07-01T14:30:03Z | |
dc.date.available | 2020-07-01T14:30:03Z | |
dc.date.issued | 2020-06-01 | |
dc.identifier.citation | Chinthal , C H , Yathirajan , H S , Archana , S D , Foro , S & Glidewell , C 2020 , ' Three 4-(4-fluorophenyl)piperazin-1-ium salts containing organic anions : supramolecular assembly in one, two and three dimensions ' , Acta Crystallographica Section E: Crystallographic Communications , vol. 76 , no. 6 , pp. 841-847 . https://doi.org/10.1107/S2056989020006398 | en |
dc.identifier.issn | 2056-9890 | |
dc.identifier.other | PURE: 268723367 | |
dc.identifier.other | PURE UUID: 0c41464c-f0fc-4ec7-942e-532141705d3d | |
dc.identifier.other | Scopus: 85086264684 | |
dc.identifier.other | WOS: 000538605700016 | |
dc.identifier.uri | https://hdl.handle.net/10023/20187 | |
dc.description | HSY thanks the University Grants Commission, New Delhi, for the award of a BSR Faculty Fellowship for three years. | en |
dc.description.abstract | Three salts containing the 4-(4-fluorophenyl)piperazin-1-ium cation have been prepared and structurally characterized. In 4-(4-fluorophenyl)piperazin-1-ium 2-hydroxy-3,5-dinitrobenzoate, C10H14FN2 +·C7H3N2O7 -, (I), the anion contains an intramolecular O-H···O hydrogen bond, and it has a structure similar to that of the picrate ion. The cations and anions are linked into [001] chains of rings by a combination of two three-centre N-H··· (O)2 hydrogen bonds. The anion in 4-(4-fluorophenyl)piperazin-1-ium hydrogen oxalate, C10H14FN2 +·C2HO4 -, (II), is planar, and the cations and anions are linked into (100) sheets by multiple hydrogen bonds including two-centre N-H···O, three-centre N-H.. (O)2, O-H···O, C-H···O and C-H··· π(arene) types. In 4-(4-fluorophenyl)piperazin-1-ium hydrogen (2R,3R)-tartrate monohydrate, C10H14FN2 +·C4H5O6 -·H2O, (III), the anion exhibits an approximate non-crystallographic twofold rotation symmetry with antiperiplanar carboxyl groups. A combination of eight hydrogen bonds, encompassing two-and three-centre N-H··· O systems, O-H···O and C-H··· π(arene) types, link the independent components into a three-dimensional framework. Comparisons are made with some related structures. | |
dc.format.extent | 7 | |
dc.language.iso | eng | |
dc.relation.ispartof | Acta Crystallographica Section E: Crystallographic Communications | en |
dc.rights | Copyright © 2020 The Author(s). This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. | en |
dc.subject | Crystal structure | en |
dc.subject | Hydrogen bonding | en |
dc.subject | Molecular conformation | en |
dc.subject | Piperazines | en |
dc.subject | Piperazinium salts | en |
dc.subject | Supramolecular assembly | en |
dc.subject | QD Chemistry | en |
dc.subject | Chemistry(all) | en |
dc.subject | Materials Science(all) | en |
dc.subject | Condensed Matter Physics | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Three 4-(4-fluorophenyl)piperazin-1-ium salts containing organic anions : supramolecular assembly in one, two and three dimensions | en |
dc.type | Journal article | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.1107/S2056989020006398 | |
dc.description.status | Peer reviewed | en |
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