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Synthesis and reactivity of [Au(NHC)(Bpin)] complexes

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Zinser_2019_CC_Synthesis_AAM.pdf (401.9Kb)
Date
14/06/2019
Author
Zinser, Caroline M.
Nahra, Fady
Falivene, Laura
Brill, Marcel
Cordes, David B.
Slawin, Alexandra M. Z.
Cavallo, Luigi
Cazin, Catherine
Nolan, Steven
Funder
The Royal Society
Grant ID
UF100691
Keywords
QD Chemistry
DAS
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Abstract
A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.
Citation
Zinser , C M , Nahra , F , Falivene , L , Brill , M , Cordes , D B , Slawin , A M Z , Cavallo , L , Cazin , C & Nolan , S 2019 , ' Synthesis and reactivity of [Au(NHC)(Bpin)] complexes ' , Chemical Communications , vol. 55 , no. 47 . https://doi.org/10.1039/C9CC03171E
Publication
Chemical Communications
Status
Peer reviewed
DOI
https://doi.org/10.1039/C9CC03171E
ISSN
1359-7345
Type
Journal article
Rights
Copyright © 2019 The Author(s). This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C9CC03171E
Description
The authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), AstraZeneca (Studenship to C.M.Z) and VLAIO (CO2PERATE) for support of this work. We thank King Saud University (DSF Program) and KAUST (Award No.OSR-2015-CCF-1974-03) for support.
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  • University of St Andrews Research
URI
http://hdl.handle.net/10023/19947

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