Synthesis and reactivity of [Au(NHC)(Bpin)] complexes
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A new class of [Au(NHC)(Bpin)] complexes has been synthesized and their unusual reactivity was investigated using computational and experimental methods. The gold-boryl complexes exhibit unexpected high stability and reactivity.
Zinser , C M , Nahra , F , Falivene , L , Brill , M , Cordes , D B , Slawin , A M Z , Cavallo , L , Cazin , C & Nolan , S 2019 , ' Synthesis and reactivity of [Au(NHC)(Bpin)] complexes ' , Chemical Communications , vol. 55 , no. 47 . https://doi.org/10.1039/C9CC03171E
Copyright © 2019 The Author(s). This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C9CC03171E
DescriptionThe authors gratefully acknowledge the Royal Society (University Research Fellowship to C.S.J.C.), AstraZeneca (Studenship to C.M.Z) and VLAIO (CO2PERATE) for support of this work. We thank King Saud University (DSF Program) and KAUST (Award No.OSR-2015-CCF-1974-03) for support.
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