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A highly active manganese catalyst for enantioselective ketone and ester hydrogenation

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dc.contributor.authorWidegren, Magnus B.
dc.contributor.authorHarkness, Gavin J.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorCordes, David B.
dc.contributor.authorClarke, Matthew L.
dc.date.accessioned2020-05-14T08:30:18Z
dc.date.available2020-05-14T08:30:18Z
dc.date.issued2017-05-08
dc.identifier251304734
dc.identifier91758ad4-7b36-4824-a1df-d11a7711dbf2
dc.identifier000400755800030
dc.identifier85018631758
dc.identifier.citationWidegren , M B , Harkness , G J , Slawin , A M Z , Cordes , D B & Clarke , M L 2017 , ' A highly active manganese catalyst for enantioselective ketone and ester hydrogenation ' , Angewandte Chemie International Edition , vol. 56 , no. 21 , pp. 5825-5828 . https://doi.org/10.1002/anie.201702406en
dc.identifier.issn1433-7851
dc.identifier.otherORCID: /0000-0002-5366-9168/work/37446795
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861556
dc.identifier.otherORCID: /0000-0002-2444-1244/work/59464609
dc.identifier.urihttps://hdl.handle.net/10023/19939
dc.description.abstractA new hydrogenation catalyst based onamanganese complex of a chiral P,N,N ligand has been found to be especially active for the hydrogenation of esters down to 0.1 mol% catalyst loading, and gives up to 97% ee in the hydrogenation of pro-chiral deactivated ketones at 30-50 degrees C.
dc.format.extent4
dc.format.extent923394
dc.language.isoeng
dc.relation.ispartofAngewandte Chemie International Editionen
dc.subjectEnantioselective catalysisen
dc.subjectEster hydrogenationen
dc.subjectFerroceneen
dc.subjectManganeseen
dc.subjectReductionen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectBDCen
dc.subjectR2Cen
dc.subject.lccQDen
dc.titleA highly active manganese catalyst for enantioselective ketone and ester hydrogenationen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. University of St Andrewsen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doi10.1002/anie.201702406
dc.description.statusPeer revieweden
dc.date.embargoedUntil2018-04-20
dc.identifier.urlhttp://hdl.handle.net/10023/13175en


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