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dc.contributor.authorShao, Jun
dc.contributor.authorStott, Lowell D.
dc.contributor.authorGray, William R.
dc.contributor.authorGreenop, Rosanna
dc.contributor.authorPecher, Ingo
dc.contributor.authorNeil, Helen L.
dc.contributor.authorCoffin, Richard B.
dc.contributor.authorDavy, Bryan
dc.contributor.authorRae, James W. B.
dc.identifier.citationShao , J , Stott , L D , Gray , W R , Greenop , R , Pecher , I , Neil , H L , Coffin , R B , Davy , B & Rae , J W B 2019 , ' Atmosphere-ocean CO 2 exchange across the last deglaciation from the boron isotope proxy ' , Paleoceanography and Paleoclimatology , vol. Early View .
dc.identifier.otherPURE: 261203329
dc.identifier.otherPURE UUID: fc36d714-2ffd-4e03-8eb0-e9619aa704ef
dc.identifier.otherRIS: urn:8B05A2B7EEC16B6A4BA5765B13383C72
dc.identifier.otherORCID: /0000-0003-3904-2526/work/64361287
dc.identifier.otherScopus: 85074838180
dc.identifier.otherWOS: 000493036800001
dc.descriptionJ. Shao and L.D. Stott were supported by an NSF grant (MG&G 1558990). W. R. Gray and R. Greenop were supported by NERC grants NE/N011716/1 and NE/N011716/1 to J.W.B. Rae. I. Pecher, H.L. Neil, and B. Davy were supported by RSNZ Marsden Fund grant UOA1022. R. Coffin was supported by a DOE-NETL contract to NRL subcontract to TAMUCC (#601970).en
dc.description.abstractIdentifying processes within the Earth System that have modulated atmospheric pCO2 during each glacial cycle of the late Pleistocene stands as one of the grand challenges in climate science. The growing array of surface ocean pH estimates from the boron isotope proxy across the last glacial termination may reveal regions of the ocean that influenced the timing and magnitude of pCO2 rise. Here we present two new boron isotope records from the subtropical‐subpolar transition zone of the Southwest Pacific that span the last 20 kyr, as well as new radiocarbon data from the same cores. The new data suggest this region was a source of carbon to the atmosphere rather than a moderate sink as it is today. Significantly higher outgassing is observed between ~16.5‐14 kyrBP, associated with increasing δ13C and [CO3]2‐ at depth, suggesting loss of carbon from the intermediate ocean to the atmosphere. We use these new boron isotope records together with existing records to build a composite pH/pCO2 curve for the surface oceans. pH disequilibrium/CO2 outgassing was widespread throughout the last deglaciation, likely explained by upwelling of CO2 from the deep/intermediate ocean. During the Holocene, a smaller outgassing peak is observed at a time of relatively stable atmospheric CO2, which may be explained by regrowth of the terrestrial biosphere countering ocean CO2 release. Our stack is likely biased toward upwelling/CO2 source regions. Nevertheless, the composite pCO2 curve provides robust evidence that various parts of the ocean were releasing CO2 to the atmosphere over the last 25 kyr.
dc.relation.ispartofPaleoceanography and Paleoclimatologyen
dc.rightsCopyright © 2019 American Geophysical Union. All Rights Reserved. This work has been made available online in accordance with publisher policies or with permission. Permission for further reuse of this content should be sought from the publisher or the rights holder. This is the final published version of the work, which was originally published at
dc.subjectGE Environmental Sciencesen
dc.subjectSDG 13 - Climate Actionen
dc.subjectSDG 15 - Life on Landen
dc.titleAtmosphere-ocean CO2 exchange across the last deglaciation from the boron isotope proxyen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Earth & Environmental Sciencesen
dc.contributor.institutionUniversity of St Andrews. St Andrews Isotope Geochemistryen
dc.description.statusPeer revieweden

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