Files in this item
A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release
Item metadata
dc.contributor.author | Henkelis, Susan E. | |
dc.contributor.author | Vornholt, Simon M. | |
dc.contributor.author | Cordes, David B. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Wheatley, Paul S. | |
dc.contributor.author | Morris, Russell E. | |
dc.date.accessioned | 2020-02-14T00:35:08Z | |
dc.date.available | 2020-02-14T00:35:08Z | |
dc.date.issued | 2019-03-28 | |
dc.identifier | 258304870 | |
dc.identifier | 7ab85f32-757a-44dd-80df-ba97cefb8caf | |
dc.identifier | 85063083197 | |
dc.identifier | 000462635300003 | |
dc.identifier.citation | Henkelis , S E , Vornholt , S M , Cordes , D B , Slawin , A M Z , Wheatley , P S & Morris , R E 2019 , ' A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release ' , CrystEngComm , vol. 21 , no. 12 , pp. 1857-1861 . https://doi.org/10.1039/C9CE00098D | en |
dc.identifier.issn | 1466-8033 | |
dc.identifier.other | crossref: 10.1039/C9CE00098D | |
dc.identifier.other | ORCID: /0000-0002-5366-9168/work/55901214 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861631 | |
dc.identifier.other | ORCID: /0000-0001-7809-0315/work/61622102 | |
dc.identifier.uri | https://hdl.handle.net/10023/19462 | |
dc.description | Funding: UK EPSRC EP/K005499/1, EP/K503162, and EP/L017008/1). | en |
dc.description.abstract | Single crystal CPO-27-Mg, -Zn and its structural isomer UTSA-74 have been prepared through use of acid modulators; salicylic acid and benzoic acid, respectively. Salicylic acid directed the synthesis of CPO-27-Mg/Zn whereas benzoic acid the synthesis of UTSA-74. Through “in-house” SCXRD, DMF was seen to bind to the Zn2+ and water to the Mg2+ metal sites in CPO-27-M. Although the synthesis conditions were analogous for UTSA-74, DMF is too large to bind due to the proximity of the binding sites. A dissolution–recrystallisation transformation was examined from UTSA-74 to CPO-27-Zn. The release of nitric oxide was measured for each material. | |
dc.format.extent | 774861 | |
dc.language.iso | eng | |
dc.relation.ispartof | CrystEngComm | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | 10.1039/C9CE00098D | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2020-02-14 | |
dc.identifier.grantnumber | EP/K005499/1 | en |
dc.identifier.grantnumber | ep/l017008/1 | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.