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dc.contributor.authorHenkelis, Susan E.
dc.contributor.authorVornholt, Simon M.
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWheatley, Paul S.
dc.contributor.authorMorris, Russell E.
dc.date.accessioned2020-02-14T00:35:08Z
dc.date.available2020-02-14T00:35:08Z
dc.date.issued2019-03-28
dc.identifier.citationHenkelis , S E , Vornholt , S M , Cordes , D B , Slawin , A M Z , Wheatley , P S & Morris , R E 2019 , ' A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release ' , CrystEngComm , vol. 21 , no. 12 , pp. 1857-1861 . https://doi.org/10.1039/C9CE00098Den
dc.identifier.issn1466-8033
dc.identifier.otherPURE: 258304870
dc.identifier.otherPURE UUID: 7ab85f32-757a-44dd-80df-ba97cefb8caf
dc.identifier.othercrossref: 10.1039/C9CE00098D
dc.identifier.otherScopus: 85063083197
dc.identifier.otherORCID: /0000-0002-5366-9168/work/55901214
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861631
dc.identifier.otherWOS: 000462635300003
dc.identifier.otherORCID: /0000-0001-7809-0315/work/61622102
dc.identifier.urihttp://hdl.handle.net/10023/19462
dc.descriptionFunding: UK EPSRC EP/K005499/1, EP/K503162, and EP/L017008/1).en
dc.description.abstractSingle crystal CPO-27-Mg, -Zn and its structural isomer UTSA-74 have been prepared through use of acid modulators; salicylic acid and benzoic acid, respectively. Salicylic acid directed the synthesis of CPO-27-Mg/Zn whereas benzoic acid the synthesis of UTSA-74. Through “in-house” SCXRD, DMF was seen to bind to the Zn2+ and water to the Mg2+ metal sites in CPO-27-M. Although the synthesis conditions were analogous for UTSA-74, DMF is too large to bind due to the proximity of the binding sites. A dissolution–recrystallisation transformation was examined from UTSA-74 to CPO-27-Zn. The release of nitric oxide was measured for each material.
dc.language.isoeng
dc.relation.ispartofCrystEngCommen
dc.rights© 2019, the Author(s). This work has been made available online in accordance with the publisher's policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C9CE00098Den
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleA single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and releaseen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C9CE00098D
dc.description.statusPeer revieweden
dc.date.embargoedUntil2020-02-14


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