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The assembly-disassembly-organization-reassembly mechanism for 3D-2D-3D transformation of germanosilicate IWW zeolite
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dc.contributor.author | Chlubna-Eliasova, Pavla | |
dc.contributor.author | Tian, Yuyang | |
dc.contributor.author | Pinar, Ana B. | |
dc.contributor.author | Kubu, Martin | |
dc.contributor.author | Cejka, Jiri | |
dc.contributor.author | Morris, Russell E. | |
dc.date.accessioned | 2020-02-12T12:30:10Z | |
dc.date.available | 2020-02-12T12:30:10Z | |
dc.date.issued | 2014-06-25 | |
dc.identifier | 157245688 | |
dc.identifier | 6949cfb4-85cf-4067-81ba-66b007366d1b | |
dc.identifier | 000338023000041 | |
dc.identifier | 84903199639 | |
dc.identifier.citation | Chlubna-Eliasova , P , Tian , Y , Pinar , A B , Kubu , M , Cejka , J & Morris , R E 2014 , ' The assembly-disassembly-organization-reassembly mechanism for 3D-2D-3D transformation of germanosilicate IWW zeolite ' , Angewandte Chemie International Edition , vol. 53 , no. 27 , pp. 7048-7052 . https://doi.org/10.1002/anie.201400600 | en |
dc.identifier.issn | 1433-7851 | |
dc.identifier.other | ORCID: /0000-0001-7809-0315/work/69029135 | |
dc.identifier.uri | https://hdl.handle.net/10023/19449 | |
dc.description | J.Č. thanks the Czech Science Foundation for the support of this research (P106/12/G015). R.E.M. thanks the Royal Society for provision of an industry fellowship and the E.P.S.R.C. for funding (EP/K025112/1). A.B.P. acknowledges the support of the European Community under a Marie Curie Intra‐European Fellowship. | en |
dc.description.abstract | Hydrolysis of germanosilicate zeolites with the IWW structure shows two different outcomes depending on the composition of the starting materials. Ge-rich IWW (Si/Ge=3.1) is disassembled into a layered material (IPC-5P), which can be reassembled into an almost pure silica IWW on treatment with diethoxydimethylsilane. Ge-poor IWW (Si/Ge=6.4) is not completely disassembled on hydrolysis, but retains some 3D connectivity. This structure can be reassembled into IWW by incorporation of Al to fill the defects left when the Ge is removed. | |
dc.format.extent | 5 | |
dc.format.extent | 560650 | |
dc.language.iso | eng | |
dc.relation.ispartof | Angewandte Chemie International Edition | en |
dc.subject | ADOR | en |
dc.subject | Germanosilicate | en |
dc.subject | IWW | en |
dc.subject | Solid-state transformation | en |
dc.subject | Zeolites | en |
dc.subject | QD Chemistry | en |
dc.subject | BDC | en |
dc.subject.lcc | QD | en |
dc.title | The assembly-disassembly-organization-reassembly mechanism for 3D-2D-3D transformation of germanosilicate IWW zeolite | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1002/anie.201400600 | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | EP/K025112/1 | en |
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