Show simple item record

Files in this item

Thumbnail
Name:
high_branched_shortchainfinalv3pdf.pdf
Size:
670.2Kb
Format:
PDF
View/Open

High iso aldehyde selectivity in the hydroformylation of short-chain alkenes

Item metadata

dc.contributor.authorIu, Leo
dc.contributor.authorFuentes, José A.
dc.contributor.authorJanka, Mesfin
dc.contributor.authorFontenot, Kevin J.
dc.contributor.authorClarke, Matthew L.
dc.date.accessioned2020-01-18T00:34:45Z
dc.date.available2020-01-18T00:34:45Z
dc.date.issued2019-02-11
dc.identifier256955760
dc.identifier22bd59a0-78d8-448e-8509-df66dd6c940c
dc.identifier85060248862
dc.identifier000458828000043
dc.identifier.citationIu , L , Fuentes , J A , Janka , M , Fontenot , K J & Clarke , M L 2019 , ' High iso aldehyde selectivity in the hydroformylation of short-chain alkenes ' , Angewandte Chemie International Edition , vol. 58 , no. 7 , pp. 2120-2124 . https://doi.org/10.1002/anie.201811888en
dc.identifier.issn1433-7851
dc.identifier.otherORCID: /0000-0002-2444-1244/work/59464634
dc.identifier.urihttps://hdl.handle.net/10023/19306
dc.descriptionThe authors thank the Eastman Chemical Company for funding (LI, and later JAF) and permission to publish. The EPSRC (EP/M003868/1) is also acknowledged for funding (JAF).en
dc.description.abstractThe hydroformylation of propene to give predominantly iso‐butanal has been achieved; class‐leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos‐biphenols and unusual solvent systems are the key to the selectivity observed.
dc.format.extent5
dc.format.extent686330
dc.language.isoeng
dc.relation.ispartofAngewandte Chemie International Editionen
dc.subjectEnantioselective catalysisen
dc.subjectFluorinated solventsen
dc.subjectHydroformylationen
dc.subjectPhosphorus ligandsen
dc.subjectRhodiumen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectBDCen
dc.subjectR2Cen
dc.subject.lccQDen
dc.titleHigh iso aldehyde selectivity in the hydroformylation of short-chain alkenesen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1002/anie.201811888
dc.description.statusPeer revieweden
dc.date.embargoedUntil2020-01-18
dc.identifier.grantnumberEP/M003868/1en


This item appears in the following Collection(s)

Show simple item record

Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.