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High iso aldehyde selectivity in the hydroformylation of short-chain alkenes

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dc.contributor.authorIu, Leo
dc.contributor.authorFuentes, José A.
dc.contributor.authorJanka, Mesfin
dc.contributor.authorFontenot, Kevin J.
dc.contributor.authorClarke, Matthew L.
dc.date.accessioned2020-01-18T00:34:45Z
dc.date.available2020-01-18T00:34:45Z
dc.date.issued2019-02-11
dc.identifier.citationIu , L , Fuentes , J A , Janka , M , Fontenot , K J & Clarke , M L 2019 , ' High iso aldehyde selectivity in the hydroformylation of short-chain alkenes ' , Angewandte Chemie International Edition , vol. 58 , no. 7 , pp. 2120-2124 . https://doi.org/10.1002/anie.201811888en
dc.identifier.issn1433-7851
dc.identifier.otherPURE: 256955760
dc.identifier.otherPURE UUID: 22bd59a0-78d8-448e-8509-df66dd6c940c
dc.identifier.otherScopus: 85060248862
dc.identifier.otherORCID: /0000-0002-2444-1244/work/59464634
dc.identifier.otherWOS: 000458828000043
dc.identifier.urihttp://hdl.handle.net/10023/19306
dc.descriptionThe authors thank the Eastman Chemical Company for funding (LI, and later JAF) and permission to publish. The EPSRC (EP/M003868/1) is also acknowledged for funding (JAF).en
dc.description.abstractThe hydroformylation of propene to give predominantly iso‐butanal has been achieved; class‐leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos‐biphenols and unusual solvent systems are the key to the selectivity observed.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofAngewandte Chemie International Editionen
dc.rightsCopyright © 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1002/anie.201811888en
dc.subjectEnantioselective catalysisen
dc.subjectFluorinated solventsen
dc.subjectHydroformylationen
dc.subjectPhosphorus ligandsen
dc.subjectRhodiumen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subjectBDCen
dc.subjectR2Cen
dc.subject.lccQDen
dc.titleHigh iso aldehyde selectivity in the hydroformylation of short-chain alkenesen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1002/anie.201811888
dc.description.statusPeer revieweden
dc.date.embargoedUntil2020-01-18


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