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dc.contributor.authorGalán, Laura Abad
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M.Z.
dc.contributor.authorJacquemin, Denis
dc.contributor.authorOgden, Mark I.
dc.contributor.authorMassi, Massimiliano
dc.contributor.authorZysman-Colman, Eli
dc.identifier.citationGalán , L A , Cordes , D B , Slawin , A M Z , Jacquemin , D , Ogden , M I , Massi , M & Zysman-Colman , E 2018 , ' Analyzing the relation between structure and aggregation induced emission (AIE) properties of iridium(III) complexes through modification of non-chromophoric ancillary ligands ' , European Journal of Inorganic Chemistry , vol. Early View .
dc.identifier.otherPURE: 256198970
dc.identifier.otherPURE UUID: bc0b3b73-5987-4a13-a2e1-61d5cd8c2207
dc.identifier.otherRIS: urn:924352CA493CE6DF239A35FCB91DA42E
dc.identifier.otherScopus: 85056645662
dc.identifier.otherORCID: /0000-0002-5366-9168/work/50743952
dc.identifier.otherORCID: /0000-0001-7183-6022/work/56639056
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861418
dc.identifier.otherWOS: 000456212200002
dc.descriptionE.Z.-C. acknowledges the University of St. Andrews and EPSRC (EP/M02105X/1) for financial support. We thank Umicore AG for the gift of materials. We thank the EPSRC UK National Mass Spectrometry Facility at Swansea University for analytical services. This work is supported by a Royal Society International Exchanges Grant and by the Australian Research Council and. LAG thanks Curtin University for the postgraduate scholarship. This work used the computational resources of the CCIPL installed in Nantes.en
dc.description.abstractUnconventionally modified dibenzoylmethane (dbm) ligands have been synthesized and successfully utilized as ancillary ligands for neutral Ir(III) complexes of the formula [Ir(dFppy)2(LX)], where dFppyH is 2-(2,4-difluorophenyl)pyridine and LX is tribenzoylmethane ( tbm ) or 1-phenyl-3-(4-(pyridin-2-yl)phenyl)propane-1,3-dione ( pydbm ). The modification of the ligands aims to prevent or enhance possible intermolecular interactions between the dFppy and/or the LX moiety in comparison with the previously reported [Ir(dFppy)2( dbm )] complex. The aggregation induced emission (AIE) properties of these complexes are significantly modulated, as a consequence of the different π-π interactions revealed by X-ray crystallography.
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen
dc.rights© 2018 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at:
dc.subjectLigand effectsen
dc.subjectQD Chemistryen
dc.titleAnalyzing the relation between structure and aggregation induced emission (AIE) properties of iridium(III) complexes through modification of non-chromophoric ancillary ligandsen
dc.typeJournal articleen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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