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Analyzing the relation between structure and aggregation induced emission (AIE) properties of iridium(III) complexes through modification of non-chromophoric ancillary ligands

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dc.contributor.authorGalán, Laura Abad
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M.Z.
dc.contributor.authorJacquemin, Denis
dc.contributor.authorOgden, Mark I.
dc.contributor.authorMassi, Massimiliano
dc.contributor.authorZysman-Colman, Eli
dc.date.accessioned2019-11-13T00:36:36Z
dc.date.available2019-11-13T00:36:36Z
dc.date.issued2018-11-13
dc.identifier256198970
dc.identifierbc0b3b73-5987-4a13-a2e1-61d5cd8c2207
dc.identifier85056645662
dc.identifier000456212200002
dc.identifier.citationGalán , L A , Cordes , D B , Slawin , A M Z , Jacquemin , D , Ogden , M I , Massi , M & Zysman-Colman , E 2018 , ' Analyzing the relation between structure and aggregation induced emission (AIE) properties of iridium(III) complexes through modification of non-chromophoric ancillary ligands ' , European Journal of Inorganic Chemistry , vol. Early View . https://doi.org/10.1002/ejic.201801118en
dc.identifier.issn1434-1948
dc.identifier.otherRIS: urn:924352CA493CE6DF239A35FCB91DA42E
dc.identifier.otherORCID: /0000-0002-5366-9168/work/50743952
dc.identifier.otherORCID: /0000-0001-7183-6022/work/56639056
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861418
dc.identifier.urihttps://hdl.handle.net/10023/18909
dc.descriptionE.Z.-C. acknowledges the University of St. Andrews and EPSRC (EP/M02105X/1) for financial support. We thank Umicore AG for the gift of materials. We thank the EPSRC UK National Mass Spectrometry Facility at Swansea University for analytical services. This work is supported by a Royal Society International Exchanges Grant and by the Australian Research Council and. LAG thanks Curtin University for the postgraduate scholarship. This work used the computational resources of the CCIPL installed in Nantes.en
dc.description.abstractUnconventionally modified dibenzoylmethane (dbm) ligands have been synthesized and successfully utilized as ancillary ligands for neutral Ir(III) complexes of the formula [Ir(dFppy)2(LX)], where dFppyH is 2-(2,4-difluorophenyl)pyridine and LX is tribenzoylmethane ( tbm ) or 1-phenyl-3-(4-(pyridin-2-yl)phenyl)propane-1,3-dione ( pydbm ). The modification of the ligands aims to prevent or enhance possible intermolecular interactions between the dFppy and/or the LX moiety in comparison with the previously reported [Ir(dFppy)2( dbm )] complex. The aggregation induced emission (AIE) properties of these complexes are significantly modulated, as a consequence of the different π-π interactions revealed by X-ray crystallography.
dc.format.extent3701754
dc.language.isoeng
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen
dc.subjectIridiumen
dc.subjectLuminescenceen
dc.subjectComplexesen
dc.subjectPhotophysicsen
dc.subjectOptoelectronicsen
dc.subjectLigand effectsen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleAnalyzing the relation between structure and aggregation induced emission (AIE) properties of iridium(III) complexes through modification of non-chromophoric ancillary ligandsen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorThe Royal Societyen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1002/ejic.201801118
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-11-13
dc.identifier.grantnumberEP/M02105X/1en
dc.identifier.grantnumberIE140044en


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