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dc.contributor.authorJohnson, Timothy
dc.contributor.authorŁozińska, Magdalena M.
dc.contributor.authorOrsi, Angelica F.
dc.contributor.authorWright, Paul A.
dc.contributor.authorHindocha, Sheena
dc.contributor.authorPoulston, Stephen
dc.date.accessioned2019-10-28T16:30:02Z
dc.date.available2019-10-28T16:30:02Z
dc.date.issued2019-10-21
dc.identifier.citationJohnson , T , Łozińska , M M , Orsi , A F , Wright , P A , Hindocha , S & Poulston , S 2019 , ' Improvements to the production of ZIF-94; a case study in MOF scale-up ' , Green Chemistry , vol. 21 , no. 20 , pp. 5665-5670 . https://doi.org/10.1039/C9GC00783Ken
dc.identifier.issn1463-9262
dc.identifier.otherPURE: 262433167
dc.identifier.otherPURE UUID: 1fa3bc6e-6324-4080-bec6-a22e07edcb5b
dc.identifier.otherBibtex: C9GC00783K
dc.identifier.otherScopus: 85073516720
dc.identifier.otherORCID: /0000-0002-4243-9957/work/64033735
dc.identifier.otherWOS: 000490291800020
dc.identifier.urihttps://hdl.handle.net/10023/18792
dc.descriptionThe authors acknowledge the financial support of the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013), under grant agreement no. 608490, M4CO2 project.en
dc.description.abstractThe ability to produce large scale quantities of MOF materials is essential for the commercialisation of these frameworks to continue. Herein we report how the production of ZIF-94 can be improved from a ∼1 g laboratory preparation to a scalable procedure allowing for large scale production of the desired framework. The synthesis of ZIF-94 was completed at room temperature, atmospheric pressure and without the use of DMF as a solvent. This method offers improvements over the current literature synthesis routes and affords a product at 18 wt% solids. To demonstrate the robustness of the derived methodology a 60 g, large scale, batch of this framework was produced which possessed a surface area of 468 m2 g−1. This large scale sample has superior CO2 uptake of 3.3 mmol g−1 at 1 bar, an improvement of 30% over literature reports.
dc.format.extent6
dc.language.isoeng
dc.relation.ispartofGreen Chemistryen
dc.rightsCopyright © 2019 The Author(s). Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.en
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleImprovements to the production of ZIF-94; a case study in MOF scale-upen
dc.typeJournal articleen
dc.contributor.sponsorEuropean Commissionen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/C9GC00783K
dc.description.statusPeer revieweden
dc.identifier.grantnumber608490en


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