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Improvements to the production of ZIF-94; a case study in MOF scale-up
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dc.contributor.author | Johnson, Timothy | |
dc.contributor.author | Łozińska, Magdalena M. | |
dc.contributor.author | Orsi, Angelica F. | |
dc.contributor.author | Wright, Paul A. | |
dc.contributor.author | Hindocha, Sheena | |
dc.contributor.author | Poulston, Stephen | |
dc.date.accessioned | 2019-10-28T16:30:02Z | |
dc.date.available | 2019-10-28T16:30:02Z | |
dc.date.issued | 2019-10-21 | |
dc.identifier.citation | Johnson , T , Łozińska , M M , Orsi , A F , Wright , P A , Hindocha , S & Poulston , S 2019 , ' Improvements to the production of ZIF-94; a case study in MOF scale-up ' , Green Chemistry , vol. 21 , no. 20 , pp. 5665-5670 . https://doi.org/10.1039/C9GC00783K | en |
dc.identifier.issn | 1463-9262 | |
dc.identifier.other | PURE: 262433167 | |
dc.identifier.other | PURE UUID: 1fa3bc6e-6324-4080-bec6-a22e07edcb5b | |
dc.identifier.other | Bibtex: C9GC00783K | |
dc.identifier.other | Scopus: 85073516720 | |
dc.identifier.other | ORCID: /0000-0002-4243-9957/work/64033735 | |
dc.identifier.other | WOS: 000490291800020 | |
dc.identifier.uri | https://hdl.handle.net/10023/18792 | |
dc.description | The authors acknowledge the financial support of the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013), under grant agreement no. 608490, M4CO2 project. | en |
dc.description.abstract | The ability to produce large scale quantities of MOF materials is essential for the commercialisation of these frameworks to continue. Herein we report how the production of ZIF-94 can be improved from a ∼1 g laboratory preparation to a scalable procedure allowing for large scale production of the desired framework. The synthesis of ZIF-94 was completed at room temperature, atmospheric pressure and without the use of DMF as a solvent. This method offers improvements over the current literature synthesis routes and affords a product at 18 wt% solids. To demonstrate the robustness of the derived methodology a 60 g, large scale, batch of this framework was produced which possessed a surface area of 468 m2 g−1. This large scale sample has superior CO2 uptake of 3.3 mmol g−1 at 1 bar, an improvement of 30% over literature reports. | |
dc.format.extent | 6 | |
dc.language.iso | eng | |
dc.relation.ispartof | Green Chemistry | en |
dc.rights | Copyright © 2019 The Author(s). Open Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Improvements to the production of ZIF-94; a case study in MOF scale-up | en |
dc.type | Journal article | en |
dc.contributor.sponsor | European Commission | en |
dc.description.version | Publisher PDF | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/C9GC00783K | |
dc.description.status | Peer reviewed | en |
dc.identifier.grantnumber | 608490 | en |
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