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Syntheses and structures of piperazin-1-ium ABr2 (A = Cs or Rb) : hybrid solids containing 'curtain wall' layers of face- and edge-sharing ABr6 trigonal prisms
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dc.contributor.author | Rickaby, Kirstie A. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Harrison, William T. A. | |
dc.date.accessioned | 2019-08-13T14:30:09Z | |
dc.date.available | 2019-08-13T14:30:09Z | |
dc.date.issued | 2019-08 | |
dc.identifier | 260560698 | |
dc.identifier | f7f74ca2-6dbc-4109-ba94-400207a0d6ba | |
dc.identifier | 85071507903 | |
dc.identifier | 000480512800032 | |
dc.identifier.citation | Rickaby , K A , Slawin , A M Z & Harrison , W T A 2019 , ' Syntheses and structures of piperazin-1-ium A Br 2 ( A = Cs or Rb) : hybrid solids containing 'curtain wall' layers of face- and edge-sharing ABr6 trigonal prisms ' , Acta Crystallographica Section E , vol. 75 , no. 8 , pp. 1249-1252 . https://doi.org/10.1107/S2056989019010375 | en |
dc.identifier.issn | 2056-9890 | |
dc.identifier.other | Bibtex: urn:6aa079199bd933d3d75f72db3eb8c730 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/60630649 | |
dc.identifier.uri | https://hdl.handle.net/10023/18309 | |
dc.description.abstract | The isostructural title compounds, poly[piperazin-1-ium [di-μ-bromido-caesium]], {(C4H11N2)[CsBr2]}n, and poly[piperazin-1-ium [di-μ-bromido-rubidium]], {(C4H11N2)[RbBr2]}n, contain singly-protonated piperazin-1-ium cations and unusual ABr6 (A = Cs or Rb) trigonal prisms. The prisms are linked into a distinctive `curtain wall' arrangement propagating in the (010) plane by face and edge sharing. In each case, a network of N—H⋯N, N—H⋯Br and N—H⋯(Br,Br) hydrogen bonds consolidates the structure. | |
dc.format.extent | 4 | |
dc.format.extent | 572082 | |
dc.language.iso | eng | |
dc.relation.ispartof | Acta Crystallographica Section E | en |
dc.subject | Crystal structure | en |
dc.subject | Hybrid solid | en |
dc.subject | Caesium | en |
dc.subject | Rubidium | en |
dc.subject | Trigonal prism | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Syntheses and structures of piperazin-1-ium ABr2 (A = Cs or Rb) : hybrid solids containing 'curtain wall' layers of face- and edge-sharing ABr6 trigonal prisms | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1107/S2056989019010375 | |
dc.description.status | Peer reviewed | en |
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