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dc.contributor.authorRickaby, Kirstie A.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorHarrison, William T. A.
dc.date.accessioned2019-08-13T14:30:09Z
dc.date.available2019-08-13T14:30:09Z
dc.date.issued2019-08
dc.identifier.citationRickaby , K A , Slawin , A M Z & Harrison , W T A 2019 , ' Syntheses and structures of piperazin-1-ium A Br 2 ( A = Cs or Rb) : hybrid solids containing 'curtain wall' layers of face- and edge-sharing ABr6 trigonal prisms ' Acta Crystallographica Section E , vol. 75 , no. 8 , pp. 1249-1252 . https://doi.org/10.1107/S2056989019010375en
dc.identifier.issn2056-9890
dc.identifier.otherPURE: 260560698
dc.identifier.otherPURE UUID: f7f74ca2-6dbc-4109-ba94-400207a0d6ba
dc.identifier.otherBibtex: urn:6aa079199bd933d3d75f72db3eb8c730
dc.identifier.otherORCID: /0000-0002-9527-6418/work/60630649
dc.identifier.urihttp://hdl.handle.net/10023/18309
dc.description.abstractThe isostructural title compounds, poly[piperazin-1-ium [di-μ-bromido-caesium]], {(C4H11N2)[CsBr2]}n, and poly[piperazin-1-ium [di-μ-bromido-rubidium]], {(C4H11N2)[RbBr2]}n, contain singly-protonated piperazin-1-ium cations and unusual ABr6 (A = Cs or Rb) trigonal prisms. The prisms are linked into a distinctive `curtain wall' arrangement propagating in the (010) plane by face and edge sharing. In each case, a network of N—H⋯N, N—H⋯Br and N—H⋯(Br,Br) hydrogen bonds consolidates the structure.
dc.format.extent4
dc.language.isoeng
dc.relation.ispartofActa Crystallographica Section Een
dc.rightsCopyright © 2019 The Author(s). This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.en
dc.subjectCrystal structureen
dc.subjectHybrid soliden
dc.subjectCaesiumen
dc.subjectRubidiumen
dc.subjectTrigonal prismen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleSyntheses and structures of piperazin-1-ium ABr2 (A = Cs or Rb) : hybrid solids containing 'curtain wall' layers of face- and edge-sharing ABr6 trigonal prismsen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1107/S2056989019010375
dc.description.statusPeer revieweden


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