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dc.contributor.authorSabetghadam, Anahid
dc.contributor.authorLiu, Xinlei
dc.contributor.authorOrsi, Angelica
dc.contributor.authorLozinska, Magdalena
dc.contributor.authorJohnson, Timothy
dc.contributor.authorJansen, Kaspar
dc.contributor.authorWright, Paul
dc.contributor.authorCarta, Mariolino
dc.contributor.authorMckeown, Neil
dc.contributor.authorKapteijn, Freek
dc.contributor.authorGascon, Jorge
dc.identifier.citationSabetghadam , A , Liu , X , Orsi , A , Lozinska , M , Johnson , T , Jansen , K , Wright , P , Carta , M , Mckeown , N , Kapteijn , F & Gascon , J 2018 , ' Towards high performance metal–organic framework - microporous polymer mixed matrix membranes : addressing compatibility and limiting aging by polymer doping ' , Chemistry - A European Journal , vol. In Press .
dc.identifier.othercrossref: 10.1002/chem.201803006
dc.identifier.otherORCID: /0000-0002-4243-9957/work/62668275
dc.descriptionThe authors gratefully acknowledge the financial support from the European Research Council under the European Union’s Seventh Framework Programme (FP/2007-2013), M4CO2 project (608490).en
dc.description.abstractMembrane separation for gas purification is an energy‐efficient and environment‐friendly technology. However, the development of high performance membranes is still a great challenge. In principle, mixed matrix membranes (MMMs) have the potential to overcome current materials limitations, but in practice there is no straightforward method to match the properties of fillers and polymers (the main components of MMMs) in such a way that the final membrane performance reflects the high performance of the microporous filler and the processability of the continuous polymer phase. This issue is especially important when high flux polymers are utilized. In this work, we demonstrate that the use of small amounts of a glassy polymer in combination with high performance PIM‐1 allow for the preparation of MOF based MMMs with superior separation properties and low aging rates under humid conditions, meeting the commercial target for post‐combustion CO2 capture.
dc.relation.ispartofChemistry - A European Journalen
dc.subjectMicroporous polymeren
dc.subjectMetal-organic frameworksen
dc.subjectQD Chemistryen
dc.titleTowards high performance metal–organic framework - microporous polymer mixed matrix membranes : addressing compatibility and limiting aging by polymer dopingen
dc.typeJournal articleen
dc.contributor.sponsorEuropean Commissionen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.description.statusPeer revieweden

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