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dc.contributor.authorHenkelis, Susan E.
dc.contributor.authorMorris, Sam A.
dc.contributor.authorMazur, Michal
dc.contributor.authorWheatley, Paul S.
dc.contributor.authorMcHugh, Lauren N.
dc.contributor.authorMorris, Russell
dc.date.accessioned2019-08-05T23:41:35Z
dc.date.available2019-08-05T23:41:35Z
dc.date.issued2018-08-06
dc.identifier255220525
dc.identifier8c924988-a32a-468a-9d7a-429419fc4009
dc.identifier85053511914
dc.identifier000445218000030
dc.identifier.citationHenkelis , S E , Morris , S A , Mazur , M , Wheatley , P S , McHugh , L N & Morris , R 2018 , ' Monitoring the assembly-disassembly-organisation-reassembly process of germanosilicate UTL through in situ pair distribution function analysis ' , Journal of Materials Chemistry , vol. In Press . https://doi.org/10.1039/C8TA04320Een
dc.identifier.issn0959-9428
dc.identifier.otherBibtex: urn:deb4d336e1106a4c8adb8a9dcbae3879
dc.identifier.otherORCID: /0000-0001-7809-0315/work/61622128
dc.identifier.urihttps://hdl.handle.net/10023/18253
dc.descriptionThe authors would like to thank: The EPSRC (grants: EP/K025112/1; EP/K005499/1; EP/K503162/1) for funding opportunities and beam line I15 at the Diamond Light Source. Phoebe Allan is acknowledged for her help and knowledge of PDF refinement. M.M. and R.E.M. would like to acknowledge OP VVV "Excellent Research Teams", project No. CZ.02.1.01/0.0/0.0/15_003/0000417 - CUCAM.en
dc.description.abstractA study into the disassembly and organisation steps of the ADOR process has been undertaken through in situ Pair Distribution Function (PDF) analysis. Three aqueous systems (water, 6 M HCl and 12 M HCl) were introduced to a parent zeolite germanosilicate UTL in a cell. Hydrolysis could be clearly seen when UTL was exposed to water over a period of 8 hr, forming the disorded layered material, IPC-1P. In hydrochloric acid, the hydrolysis step is too quick to observe and a Ge-Cl containing species could be seen. In 6 M HCl, the rearrangement of the interlayer region began after an induction period of 8 hr, with the process still occuring after 15 hr. In 12 M HCl, the rearrangement appears to have come to an end after only 6 hr.
dc.format.extent9
dc.format.extent1913789
dc.language.isoeng
dc.relation.ispartofJournal of Materials Chemistryen
dc.subjectQD Chemistryen
dc.subjectNDASen
dc.subject.lccQDen
dc.titleMonitoring the assembly-disassembly-organisation-reassembly process of germanosilicate UTL through in situ pair distribution function analysisen
dc.typeJournal articleen
dc.contributor.sponsorEPSRCen
dc.contributor.sponsorEPSRCen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1039/C8TA04320E
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-08-06
dc.identifier.grantnumberEP/K025112/1en
dc.identifier.grantnumberEP/K005499/1en


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