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dc.contributor.authorHowells, Calvyn T.
dc.contributor.authorSaylan, Sueda
dc.contributor.authorKim, Haeri
dc.contributor.authorMarbou, Khalid
dc.contributor.authorAoyama, Tetsua
dc.contributor.authorNakao, Aiko
dc.contributor.authorUchiyama, Masanobu
dc.contributor.authorSamuel, Ifor D. W.
dc.contributor.authorKim, Dong Wook
dc.contributor.authorDahlem, Marcus S.
dc.contributor.authorAndré, Pascal
dc.identifier.citationHowells , C T , Saylan , S , Kim , H , Marbou , K , Aoyama , T , Nakao , A , Uchiyama , M , Samuel , I D W , Kim , D W , Dahlem , M S & André , P 2018 , ' Influence of perfluorinated ionomer in PEDOT:PSS on the rectification and degradation of organic photovoltaic cells ' , Journal of Materials Chemistry A , vol. 6 , no. 33 , pp. 16012-16028 .
dc.identifier.otherPURE: 255750145
dc.identifier.otherPURE UUID: 9d95442c-cb03-41f0-b23a-2f0af63aa1a3
dc.identifier.otherScopus: 85052002245
dc.identifier.otherWOS: 000443272700009
dc.descriptionPA thanks the Canon Foundation in Europe for supporting his visits to the RIKEN through a personal Fellowship, and the Organic Semiconductor Centre of the University of St Andrews for access to facilities. IDWS and CTH acknowledge support from the Engineering and Physical Sciences Research Council of the U.K. (grants EP/L012294/1 and CTH’s studentship). IDWS also acknowledges support from a Royal Society Wolfson Research Merit Award.en
dc.description.abstractPoly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is widely used to build optoelectronic devices. However, as a hygroscopic water-based acidic material, it brings major concerns for stability and degradation, resulting in an intense effort to replace it in organic photovoltaic (OPV) devices. In this work, we focus on the perfluorinated ionomer (PFI) polymeric additive to PEDOT:PSS. We demonstrate that it can reduce the relative amplitude of OPV device burn-in, and find two distinct regimes of influence. At low concentrations there is a subtle effect on wetting and work function, for instance, with a detrimental impact on the device characteristics, and above a threshold it changes the electronic and device properties. The abrupt threshold in the conducting polymer occurs for PFI concentrations greater than or equal to the PSS concentration and was revealed by monitoring variations in transmission, topography, work-function, wettability and OPV device characteristics. Below this PFI concentration threshold, the power conversion efficiency (PCE) of OPVs based on poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl-C61-butyric acid methyl ester (P3HT:PCBM) are impaired largely by low fill-factors due to poor charge extraction. Above the PFI concentration threshold, we recover the PCE before it is improved beyond the pristine PEDOT:PSS layer based OPV devices. Supplementary to the performance enhancement, PFI improves OPV device stability and lifetime. Our degradation study leads to the conclusion that PFI prevents water from diffusing to and from the hygroscopic PEDOT:PSS layer, which slows down the deterioration of the PEDOT:PSS layer and the aluminum electrode. These findings reveal mechanisms and opportunities that should be taken into consideration when developing components to inhibit OPV degradation.
dc.relation.ispartofJournal of Materials Chemistry Aen
dc.rights© 2018 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at
dc.subjectQD Chemistryen
dc.subjectRenewable Energy, Sustainability and the Environmenten
dc.subjectMaterials Science(all)en
dc.titleInfluence of perfluorinated ionomer in PEDOT:PSS on the rectification and degradation of organic photovoltaic cellsen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews.Condensed Matter Physicsen
dc.contributor.institutionUniversity of St Andrews.School of Physics and Astronomyen
dc.contributor.institutionUniversity of St Andrews.Organic Semiconductor Centreen
dc.description.statusPeer revieweden

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