Show simple item record

Files in this item

Thumbnail

Item metadata

dc.contributor.authorSidirodopous, Anastas
dc.contributor.authorStasch, Andreas
dc.contributor.authorJones, Cameron
dc.date.accessioned2019-07-22T14:30:05Z
dc.date.available2019-07-22T14:30:05Z
dc.date.issued2019-07-16
dc.identifier.citationSidirodopous , A , Stasch , A & Jones , C 2019 , ' Thermal rearrangement of a 1,2-bis(silylene) : synthesis and crystal structure of a silyl-silylene ' , Main Group Metal Chemistry , vol. 42 , no. 1 , mgmc-2019-0013 , pp. 121-124 . https://doi.org/10.1515/mgmc-2019-0013en
dc.identifier.issn0792-1241
dc.identifier.otherPURE: 260258124
dc.identifier.otherPURE UUID: 475774a8-00f1-4e1c-b71e-36761c1b7075
dc.identifier.otherORCID: /0000-0002-7407-8287/work/59953724
dc.identifier.otherScopus: 85069765050
dc.identifier.urihttp://hdl.handle.net/10023/18148
dc.descriptionThis research was supported by the Australian Research Council.en
dc.description.abstractThermal rearrangement of the 1,2-bis(silylene), [{(4-ButPh)C(NDip)2}Si−]2 (Dip = 2,6-diisopropylphenyl, leads to the silyl-silylene, {(4-ButPh)C(NDip)2}Si−Si(H) {N(Dip)C(=NDip)(4-ButPh-H)}, via an intramolecular C−H activation reaction. The X-ray crystal structure, and limited spectroscopic data, for the compound are reported. The structure of the silyl-silylene incorporates an exocyclic imine fragment, which is unprecedented for this compound class.
dc.format.extent4
dc.language.isoeng
dc.relation.ispartofMain Group Metal Chemistryen
dc.rightsCopyright © 2019 Sidiropoulos et al., published by De Gruyter. This work is licensed under the Creative Commons Attribution 4.0 Public License. BY 4.0en
dc.subjectSilyleneen
dc.subjectSilyl-Silyleneen
dc.subjectBis(silylene)en
dc.subjectLow-oxidation stateen
dc.subjectX-ray crystallographyen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleThermal rearrangement of a 1,2-bis(silylene) : synthesis and crystal structure of a silyl-silyleneen
dc.typeJournal articleen
dc.description.versionPublisher PDFen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.identifier.doihttps://doi.org/10.1515/mgmc-2019-0013
dc.description.statusPeer revieweden


This item appears in the following Collection(s)

Show simple item record