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Thermal rearrangement of a 1,2-bis(silylene) : synthesis and crystal structure of a silyl-silylene
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dc.contributor.author | Sidirodopous, Anastas | |
dc.contributor.author | Stasch, Andreas | |
dc.contributor.author | Jones, Cameron | |
dc.date.accessioned | 2019-07-22T14:30:05Z | |
dc.date.available | 2019-07-22T14:30:05Z | |
dc.date.issued | 2019-07-16 | |
dc.identifier | 260258124 | |
dc.identifier | 475774a8-00f1-4e1c-b71e-36761c1b7075 | |
dc.identifier | 85069765050 | |
dc.identifier.citation | Sidirodopous , A , Stasch , A & Jones , C 2019 , ' Thermal rearrangement of a 1,2-bis(silylene) : synthesis and crystal structure of a silyl-silylene ' , Main Group Metal Chemistry , vol. 42 , no. 1 , mgmc-2019-0013 , pp. 121-124 . https://doi.org/10.1515/mgmc-2019-0013 | en |
dc.identifier.issn | 0792-1241 | |
dc.identifier.other | ORCID: /0000-0002-7407-8287/work/59953724 | |
dc.identifier.uri | https://hdl.handle.net/10023/18148 | |
dc.description | This research was supported by the Australian Research Council. | en |
dc.description.abstract | Thermal rearrangement of the 1,2-bis(silylene), [{(4-ButPh)C(NDip)2}Si−]2 (Dip = 2,6-diisopropylphenyl, leads to the silyl-silylene, {(4-ButPh)C(NDip)2}Si−Si(H) {N(Dip)C(=NDip)(4-ButPh-H)}, via an intramolecular C−H activation reaction. The X-ray crystal structure, and limited spectroscopic data, for the compound are reported. The structure of the silyl-silylene incorporates an exocyclic imine fragment, which is unprecedented for this compound class. | |
dc.format.extent | 4 | |
dc.format.extent | 636762 | |
dc.language.iso | eng | |
dc.relation.ispartof | Main Group Metal Chemistry | en |
dc.subject | Silylene | en |
dc.subject | Silyl-Silylene | en |
dc.subject | Bis(silylene) | en |
dc.subject | Low-oxidation state | en |
dc.subject | X-ray crystallography | en |
dc.subject | QD Chemistry | en |
dc.subject | DAS | en |
dc.subject.lcc | QD | en |
dc.title | Thermal rearrangement of a 1,2-bis(silylene) : synthesis and crystal structure of a silyl-silylene | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.identifier.doi | https://doi.org/10.1515/mgmc-2019-0013 | |
dc.description.status | Peer reviewed | en |
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