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Energy transfer between Eu3+ and Nd3+ in near-infrared emitting β-triketonate coordination polymers
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dc.contributor.author | Abad Galán, Laura | |
dc.contributor.author | Sobolev, Alexandre | |
dc.contributor.author | Skelton, Brian | |
dc.contributor.author | Zysman-Colman, Eli | |
dc.contributor.author | Ogden, Mark | |
dc.contributor.author | Massi, Massimiliano | |
dc.date.accessioned | 2019-07-19T23:41:15Z | |
dc.date.available | 2019-07-19T23:41:15Z | |
dc.date.issued | 2018-07-20 | |
dc.identifier | 255154577 | |
dc.identifier | 13e0c5e6-01de-432d-b4ae-78c52af3c7d8 | |
dc.identifier | 85053436853 | |
dc.identifier | 000444400200033 | |
dc.identifier.citation | Abad Galán , L , Sobolev , A , Skelton , B , Zysman-Colman , E , Ogden , M & Massi , M 2018 , ' Energy transfer between Eu 3+ and Nd 3+ in near-infrared emitting β-triketonate coordination polymers ' , Dalton Transactions , vol. In press . https://doi.org/10.1039/C8DT02499E | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | ORCID: /0000-0001-7183-6022/work/56639039 | |
dc.identifier.uri | https://hdl.handle.net/10023/18139 | |
dc.description | This research was partially supported by the Australian Research Council's Discovery Projects funding scheme (project DP17010189), and a Royal Society International Exchanges Grant. E.Z.-C. thanks the EPSRC (EP/M02105X/1) for support. L.A.G thanks Curtin University for the Australian Postgraduate Award. | en |
dc.description.abstract | Isomorphous β-triketonate-based lanthanoid polymers containing tris(4-methylbenzoyl)methanide ( mtbm ) and Rb+ with formula {[Ln(Rb)( mtbm )4]2}n (Ln = Eu3+ and Nd3+) have been synthesised and structurally characterised. The photophysical properties for the Nd3+ complex presented relatively long lifetimes and high quantum yields in comparison with analogous β-diketonate complexes. Mixed lanthanoid complexes were also formed and their luminescence properties studied, with effective sensitisation of the 4F3/2 of Nd3+ via the 5D0 of Eu3+, which is to the best of our knowledge the first example of Eu3+ to Nd3+ sensitisation in a structurally defined coordination complex or polymer. | |
dc.format.extent | 1216092 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.subject | QD Chemistry | en |
dc.subject | NDAS | en |
dc.subject.lcc | QD | en |
dc.title | Energy transfer between Eu3+ and Nd3+ in near-infrared emitting β-triketonate coordination polymers | en |
dc.type | Journal article | en |
dc.contributor.sponsor | EPSRC | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. Organic Semiconductor Centre | en |
dc.identifier.doi | https://doi.org/10.1039/C8DT02499E | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2019-07-20 | |
dc.identifier.url | http://www.rsc.org/suppdata/c8/dt/c8dt02499e/c8dt02499e1.pdf | en |
dc.identifier.grantnumber | EP/M02105X/1 | en |
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