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dc.contributor.authorSetifi, Zouaoui
dc.contributor.authorGeiger, David
dc.contributor.authorJelsch, Christian
dc.contributor.authorMaris, Thierry
dc.contributor.authorGlidewell, Christopher
dc.contributor.authorMirzaei, Masoud
dc.contributor.authorArefian, Mina
dc.contributor.authorSetifi, Fatima
dc.date.accessioned2019-07-16T23:41:01Z
dc.date.available2019-07-16T23:41:01Z
dc.date.issued2018-12-05
dc.identifier.citationSetifi , Z , Geiger , D , Jelsch , C , Maris , T , Glidewell , C , Mirzaei , M , Arefian , M & Setifi , F 2018 , ' The first Fe(II) complex bearing end-to-end dicyanamide as a double bridging ligand : crystallography study and Hirshfeld surface analysis; completed with a CSD survey ' , Journal of Molecular Structure , vol. 1173 , pp. 697-706 . https://doi.org/10.1016/j.molstruc.2018.07.049en
dc.identifier.issn0022-2860
dc.identifier.otherPURE: 254990581
dc.identifier.otherPURE UUID: 74dc27b9-2ae8-4e81-b880-dec29d477a5d
dc.identifier.otherRIS: urn:B9B4CB9E8C95E18B4051C70A40D5DC98
dc.identifier.otherScopus: 85053104765
dc.identifier.otherWOS: 000446286200079
dc.identifier.urihttps://hdl.handle.net/10023/18104
dc.descriptionThe authors are indebted to the Algerian DG-RSDT (Direction Générale de la Recherche Scientifique et du Développement Technologique) and Université Ferhat Abbas Sétif 1. M.M. is grateful to Ferdowsi University of Mashhad Research Council for their financial support of this work.en
dc.description.abstractTwo new polymeric, one and two-dimensional compounds [Fe(dmbpy) (μ1,5-dca)2] ( 1 ) and [Fe(4,4′-bpy) (μ1,5-dca)2].0.24(4,4′-bpy).0.5(EtOH) ( 2 ), in which dmbpy = 5,5′-dimethyl-bipyridine, dca = dicyanamide and 4,4′-bpy = 4,4′-bipyridine, has been synthesized under solvothermal conditions and fully characterized by elemental analysis, FT-IR spectroscopy and X-ray single crystal diffraction. Compound 1 , with a rare coordination environment, is the only well-known example in which end-to-end double bridged dca ligands and a bidentate bulky aromatic ligand (dmbpy) are coordinated simultaneously to the iron center. Structural analysis of compound 2 showed it is a novel two-dimensional coordination polymer, constructed from repetition of 4,4′-bpy and dca as a bidentate bridging ligand. Changing the co-ligand to 4,4′-bpy, lead to completely different structure geometry and network, which confirms the substantial effect of co-ligand. Furthermore, Hirshfeld surfaces analyses have been performed to help understand the packing.
dc.format.extent10
dc.language.isoeng
dc.relation.ispartofJournal of Molecular Structureen
dc.rights© 2018 Elsevier B.V. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at: https://doi.org/10.1016/j.molstruc.2018.07.049en
dc.subjectCrystal engineeringen
dc.subjectIronen
dc.subjectDicyanamideen
dc.subjectDouble bridgeen
dc.subjectHirshfeld surface analysisen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleThe first Fe(II) complex bearing end-to-end dicyanamide as a double bridging ligand : crystallography study and Hirshfeld surface analysis; completed with a CSD surveyen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.identifier.doihttps://doi.org/10.1016/j.molstruc.2018.07.049
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-07-17
dc.identifier.urlhttps://www.sciencedirect.com/science/article/pii/S0022286018308688#appsec1en


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