(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes
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The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]para- cyclophane (PCP) skeleton with stacked (coplanar) donor-acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.
Spuling , E , Sharma , N , Samuel , I , Zysman-Colman , E & Bräse , S 2018 , ' (Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes ' Chemical Communications , vol. In press . https://doi.org/10.1039/C8CC04594A
© 2018 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C8CC04594A
DescriptionE. S. and S. B. acknowledge funding from DFG in the frame of SFB1176 (projects A4, B3 and C6) and KSOP (fellowship to E. S.). E. Z.-C. and I. D. W. S. thank the Engineering and Physical Sciences Research Council (EPSRC) (No. EP/P010482/1) for financial support. I.D.W.S. also acknowledges support from a Royal Society Wolfson Research Merit Award.
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