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(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes

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Cyclophane_paper_submitted_ver_8.pdf (1.498Mb)
Date
04/07/2018
Author
Spuling, Eduard
Sharma, Nidhi
Samuel, Ifor
Zysman-Colman, Eli
Bräse, Stefan
Funder
The Royal Society
EPSRC
EPSRC
Grant ID
NF171163
EP/P010482/1
EP/P010482/1
Keywords
QD Chemistry
DAS
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Abstract
The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]para- cyclophane (PCP) skeleton with stacked (coplanar) donor-acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.
Citation
Spuling , E , Sharma , N , Samuel , I , Zysman-Colman , E & Bräse , S 2018 , ' (Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes ' , Chemical Communications , vol. In press . https://doi.org/10.1039/C8CC04594A
Publication
Chemical Communications
Status
Peer reviewed
DOI
https://doi.org/10.1039/C8CC04594A
ISSN
1359-7345
Type
Journal article
Rights
© 2018 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C8CC04594A
Description
E. S. and S. B. acknowledge funding from DFG in the frame of SFB1176 (projects A4, B3 and C6) and KSOP (fellowship to E. S.). E. Z.-C. and I. D. W. S. thank the Engineering and Physical Sciences Research Council (EPSRC) (No. EP/P010482/1) for financial support. I.D.W.S. also acknowledges support from a Royal Society Wolfson Research Merit Award.
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  • University of St Andrews Research
URL
http://www.rsc.org/suppdata/c8/cc/c8cc04594a/c8cc04594a1.pdf
URI
http://hdl.handle.net/10023/18040

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