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dc.contributor.authorGil-Ramírez, Guzmán
dc.contributor.authorShah, Anokhi
dc.contributor.authorEl Mkami, Hassane
dc.contributor.authorPorfyrakis, Kyriakos
dc.contributor.authorBriggs, Andrew D.
dc.contributor.authorMorton, John J. L.
dc.contributor.authorAnderson, Harry L.
dc.contributor.authorLovett, Janet Eleanor
dc.date.accessioned2019-06-01T23:37:45Z
dc.date.available2019-06-01T23:37:45Z
dc.date.issued2018-06-20
dc.identifier.citationGil-Ramírez , G , Shah , A , El Mkami , H , Porfyrakis , K , Briggs , A D , Morton , J J L , Anderson , H L & Lovett , J E 2018 , ' Distance measurement of a noncovalently bound Y@C 82 Pair with double electron electron resonance spectroscopy ' , Journal of the American Chemical Society , vol. 140 , no. 24 , pp. 7420-7424 . https://doi.org/10.1021/jacs.8b03889en
dc.identifier.issn0002-7863
dc.identifier.otherPURE: 253289793
dc.identifier.otherPURE UUID: a3dd2ac7-c0ec-4b5f-a7b7-ebd0c036fb6b
dc.identifier.otherScopus: 85048044198
dc.identifier.otherORCID: /0000-0002-3561-450X/work/46569341
dc.identifier.otherORCID: /0000-0002-0552-5784/work/60195402
dc.identifier.otherWOS: 000436211600012
dc.identifier.urihttp://hdl.handle.net/10023/17799
dc.descriptionWe thank the EPSRC (EP/I035536/1; EP/J015067/1), The Royal Society (University Research Fellowship to JEL) and Wellcome Trust (099149/Z/12/Z) for funding and the EPSRC UK National Mass Spectrometry Facility at Swansea University for mass spectra.en
dc.description.abstractParamagnetic endohedral fullerenes with long spin coherence times, such as N@C60 and Y@C82, are being explored as potential spin quantum bits (qubits). Their use for quantum information processing requires a ways to hold them in fixed spatial arrangements. Here we report the synthesis of a porphyrin-based two-site receptor 1 , offering a rigid structure that binds spin-active fullerenes (Y@C82) at a center-to-center distance of 5.0 nm, predicted from molecular simulations. The spin-spin dipolar coupling was measured with the pulsed EPR spectroscopy technique of double electron electron resonance (DEER) and analysed to give a distance of 4.87 nm with a small distribution of distances.
dc.language.isoeng
dc.relation.ispartofJournal of the American Chemical Societyen
dc.rights© 2018, American Chemical Society. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1021/jacs.8b03889en
dc.subjectQC Physicsen
dc.subjectQH301 Biologyen
dc.subjectTK Electrical engineering. Electronics Nuclear engineeringen
dc.subjectDASen
dc.subject.lccQCen
dc.subject.lccQH301en
dc.subject.lccTKen
dc.titleDistance measurement of a noncovalently bound Y@C82 Pair with double electron electron resonance spectroscopyen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Physics and Astronomyen
dc.contributor.institutionUniversity of St Andrews.Biomedical Sciences Research Complexen
dc.identifier.doihttps://doi.org/10.1021/jacs.8b03889
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-06-02


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