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Distance measurement of a noncovalently bound Y@C82 Pair with double electron electron resonance spectroscopy
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dc.contributor.author | Gil-Ramírez, Guzmán | |
dc.contributor.author | Shah, Anokhi | |
dc.contributor.author | El Mkami, Hassane | |
dc.contributor.author | Porfyrakis, Kyriakos | |
dc.contributor.author | Briggs, Andrew D. | |
dc.contributor.author | Morton, John J. L. | |
dc.contributor.author | Anderson, Harry L. | |
dc.contributor.author | Lovett, Janet Eleanor | |
dc.date.accessioned | 2019-06-01T23:37:45Z | |
dc.date.available | 2019-06-01T23:37:45Z | |
dc.date.issued | 2018-06-20 | |
dc.identifier.citation | Gil-Ramírez , G , Shah , A , El Mkami , H , Porfyrakis , K , Briggs , A D , Morton , J J L , Anderson , H L & Lovett , J E 2018 , ' Distance measurement of a noncovalently bound Y@C 82 Pair with double electron electron resonance spectroscopy ' , Journal of the American Chemical Society , vol. 140 , no. 24 , pp. 7420-7424 . https://doi.org/10.1021/jacs.8b03889 | en |
dc.identifier.issn | 0002-7863 | |
dc.identifier.other | PURE: 253289793 | |
dc.identifier.other | PURE UUID: a3dd2ac7-c0ec-4b5f-a7b7-ebd0c036fb6b | |
dc.identifier.other | Scopus: 85048044198 | |
dc.identifier.other | ORCID: /0000-0002-3561-450X/work/46569341 | |
dc.identifier.other | ORCID: /0000-0002-0552-5784/work/60195402 | |
dc.identifier.other | WOS: 000436211600012 | |
dc.identifier.uri | https://hdl.handle.net/10023/17799 | |
dc.description | We thank the EPSRC (EP/I035536/1; EP/J015067/1), The Royal Society (University Research Fellowship to JEL) and Wellcome Trust (099149/Z/12/Z) for funding and the EPSRC UK National Mass Spectrometry Facility at Swansea University for mass spectra. | en |
dc.description.abstract | Paramagnetic endohedral fullerenes with long spin coherence times, such as N@C60 and Y@C82, are being explored as potential spin quantum bits (qubits). Their use for quantum information processing requires a ways to hold them in fixed spatial arrangements. Here we report the synthesis of a porphyrin-based two-site receptor 1 , offering a rigid structure that binds spin-active fullerenes (Y@C82) at a center-to-center distance of 5.0 nm, predicted from molecular simulations. The spin-spin dipolar coupling was measured with the pulsed EPR spectroscopy technique of double electron electron resonance (DEER) and analysed to give a distance of 4.87 nm with a small distribution of distances. | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of the American Chemical Society | en |
dc.rights | © 2018, American Chemical Society. This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1021/jacs.8b03889 | en |
dc.subject | QC Physics | en |
dc.subject | QH301 Biology | en |
dc.subject | TK Electrical engineering. Electronics Nuclear engineering | en |
dc.subject | DAS | en |
dc.subject.lcc | QC | en |
dc.subject.lcc | QH301 | en |
dc.subject.lcc | TK | en |
dc.title | Distance measurement of a noncovalently bound Y@C82 Pair with double electron electron resonance spectroscopy | en |
dc.type | Journal article | en |
dc.contributor.sponsor | The Royal Society | en |
dc.contributor.sponsor | The Wellcome Trust | en |
dc.contributor.sponsor | The Royal Society | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Physics and Astronomy | en |
dc.contributor.institution | University of St Andrews. Biomedical Sciences Research Complex | en |
dc.identifier.doi | https://doi.org/10.1021/jacs.8b03889 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2019-06-02 | |
dc.identifier.grantnumber | UF090121 | en |
dc.identifier.grantnumber | 099149/Z/12/Z | en |
dc.identifier.grantnumber | UF150698 | en |
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