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Distance measurement of a noncovalently bound Y@C82 Pair with double electron electron resonance spectroscopy
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dc.contributor.author | Gil-Ramírez, Guzmán | |
dc.contributor.author | Shah, Anokhi | |
dc.contributor.author | El Mkami, Hassane | |
dc.contributor.author | Porfyrakis, Kyriakos | |
dc.contributor.author | Briggs, Andrew D. | |
dc.contributor.author | Morton, John J. L. | |
dc.contributor.author | Anderson, Harry L. | |
dc.contributor.author | Lovett, Janet Eleanor | |
dc.date.accessioned | 2019-06-01T23:37:45Z | |
dc.date.available | 2019-06-01T23:37:45Z | |
dc.date.issued | 2018-06-20 | |
dc.identifier | 253289793 | |
dc.identifier | a3dd2ac7-c0ec-4b5f-a7b7-ebd0c036fb6b | |
dc.identifier | 85048044198 | |
dc.identifier | 000436211600012 | |
dc.identifier.citation | Gil-Ramírez , G , Shah , A , El Mkami , H , Porfyrakis , K , Briggs , A D , Morton , J J L , Anderson , H L & Lovett , J E 2018 , ' Distance measurement of a noncovalently bound Y@C 82 Pair with double electron electron resonance spectroscopy ' , Journal of the American Chemical Society , vol. 140 , no. 24 , pp. 7420-7424 . https://doi.org/10.1021/jacs.8b03889 | en |
dc.identifier.issn | 0002-7863 | |
dc.identifier.other | ORCID: /0000-0002-3561-450X/work/46569341 | |
dc.identifier.other | ORCID: /0000-0002-0552-5784/work/60195402 | |
dc.identifier.uri | https://hdl.handle.net/10023/17799 | |
dc.description | We thank the EPSRC (EP/I035536/1; EP/J015067/1), The Royal Society (University Research Fellowship to JEL) and Wellcome Trust (099149/Z/12/Z) for funding and the EPSRC UK National Mass Spectrometry Facility at Swansea University for mass spectra. | en |
dc.description.abstract | Paramagnetic endohedral fullerenes with long spin coherence times, such as N@C60 and Y@C82, are being explored as potential spin quantum bits (qubits). Their use for quantum information processing requires a ways to hold them in fixed spatial arrangements. Here we report the synthesis of a porphyrin-based two-site receptor 1 , offering a rigid structure that binds spin-active fullerenes (Y@C82) at a center-to-center distance of 5.0 nm, predicted from molecular simulations. The spin-spin dipolar coupling was measured with the pulsed EPR spectroscopy technique of double electron electron resonance (DEER) and analysed to give a distance of 4.87 nm with a small distribution of distances. | |
dc.format.extent | 733102 | |
dc.language.iso | eng | |
dc.relation.ispartof | Journal of the American Chemical Society | en |
dc.subject | QC Physics | en |
dc.subject | QH301 Biology | en |
dc.subject | TK Electrical engineering. Electronics Nuclear engineering | en |
dc.subject | DAS | en |
dc.subject.lcc | QC | en |
dc.subject.lcc | QH301 | en |
dc.subject.lcc | TK | en |
dc.title | Distance measurement of a noncovalently bound Y@C82 Pair with double electron electron resonance spectroscopy | en |
dc.type | Journal article | en |
dc.contributor.sponsor | The Royal Society | en |
dc.contributor.sponsor | The Wellcome Trust | en |
dc.contributor.sponsor | The Royal Society | en |
dc.contributor.institution | University of St Andrews. School of Physics and Astronomy | en |
dc.contributor.institution | University of St Andrews. Biomedical Sciences Research Complex | en |
dc.identifier.doi | https://doi.org/10.1021/jacs.8b03889 | |
dc.description.status | Peer reviewed | en |
dc.date.embargoedUntil | 2019-06-02 | |
dc.identifier.grantnumber | UF090121 | en |
dc.identifier.grantnumber | 099149/Z/12/Z | en |
dc.identifier.grantnumber | UF150698 | en |
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