Show simple item record

Files in this item

Thumbnail

Item metadata

dc.contributor.authorClark, L
dc.contributor.authorPimenta, V
dc.contributor.authorLhoste, J
dc.contributor.authorda Silva, I
dc.contributor.authorPayen, C
dc.contributor.authorGrenèche, J.-M.
dc.contributor.authorMaisonneuve, V
dc.contributor.authorLightfoot, Philip
dc.contributor.authorLeblanc, M
dc.date.accessioned2019-05-27T09:30:02Z
dc.date.available2019-05-27T09:30:02Z
dc.date.issued2019-07
dc.identifier.citationClark , L , Pimenta , V , Lhoste , J , da Silva , I , Payen , C , Grenèche , J-M , Maisonneuve , V , Lightfoot , P & Leblanc , M 2019 , ' Strong magnetic exchange and frustrated ferrimagnetic order in a weberite-type inorganic-organic hybrid fluoride ' , Philosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciences , vol. 377 , no. 2149 . https://doi.org/10.1098/rsta.2018.0224en
dc.identifier.issn1364-503X
dc.identifier.otherPURE: 258479433
dc.identifier.otherPURE UUID: 5c886173-2d77-410c-b2c2-01f29627b8b6
dc.identifier.otherScopus: 85066949551
dc.identifier.otherWOS: 000469033400005
dc.identifier.otherORCID: /0000-0001-7048-3982/work/62668228
dc.identifier.urihttp://hdl.handle.net/10023/17763
dc.descriptionLC acknowledges the University of Liverpool for start-up funding and support. Work at the University of St Andrews was supported by a Leverhulme Research Project Grant. Access to beam time at the ISIS Neutron and Muon Facility was supported by the Science and Technology Facilities Council. The authors also gratefully acknowledge Delphine Toulemon, ITODYS, UMR7086 CNRS, Université Paris VII, for assistance with magnetisation measurements.en
dc.description.abstractWe combine powder neutron diffraction, magnetometry and 57Fe Mössbauer spectrometry to determine the nuclear and magnetic structures of a strongly interacting weberite-type inorganic-organic hybrid fluoride, Fe2F5(Htaz). In this structure, Fe2+ and Fe3+ cations form magnetically frustrated hexagonal tungsten bronze (HTB) layers of corner sharing octahedra. Our powder neutron diffraction data reveal that, unlike its purely inorganic fluoride weberite counterparts which adopt a centrosymmetric Imma structure, the room- temperature nuclear structure of Fe2F5(Htaz) is best described by a non centrosymmetric Ima2 model with refined lattice parameters a = 9.1467(2) Å, b = 9.4641(2) Å and c = 7.4829(2) Å. Magnetic susceptibility and magnetisation measurements reveal that strong antiferromagnetic exchange interactions prevail in Fe2F5(Htaz) leading to a magnetic ordering transition at TN = 93 K. Analysis of low-temperature powder neutron diffraction data indicates that below TN, the Fe2+ sublattice is ferromagnetic, with a moment of 4.1(1) μB per Fe2+ at 2 K, but that an antiferromagnetic component of 0.6(3) μB cants the main ferromagnetic component of Fe3+, which aligns antiferromagnetically to the Fe2+ sublattice. The zero-field and in-field Mössbauer spectra give clear evidence of an excess of high-spin Fe3+ species within the structure and a non collinear magnetic structure.
dc.language.isoeng
dc.relation.ispartofPhilosophical Transactions of the Royal Society. A, Mathematical, Physical and Engineering Sciencesen
dc.rightsCopyright © 2019 The Author(s). This work has been made available online in accordance with the publisher’s policies. This is the author created, accepted version manuscript following peer review and may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1098/rsta.2018.0224en
dc.subjectNeutron diffractionen
dc.subjectFluoridesen
dc.subject57Fe Mössbauer spectrometryen
dc.subjectCoordination frameworksen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleStrong magnetic exchange and frustrated ferrimagnetic order in a weberite-type inorganic-organic hybrid fluorideen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.identifier.doihttps://doi.org/10.1098/rsta.2018.0224
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-05-26


This item appears in the following Collection(s)

Show simple item record