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Title: Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)]
Authors: Slawin, Alexandra M. Z.
Waddell, Paul G.
Woollins, J. Derek
Keywords: QD Chemistry
Issue Date: May-2010
Citation: Slawin , A M Z , Waddell , P G & Woollins , J D 2010 , ' Di-mu-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)] ' Acta Crystallographica. Section E, Structure reports online , vol 66 , no. 5 , pp. M499-U317 . , 10.1107/S1600536810012055
Abstract: The title compound, [Pd2Cl4(C8H11O2P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd center dot center dot center dot Pd distance of 3.4662 (17) angstrom. It has a similar geometry to that observed in the triphenylphosphite and triphenylphosphine analogues. The Pd-P bond length is ca 0.04 angstrom shorter than those in mononuclear PdCl2(P(OMe)(2)Ph)(2), possibly due to the lower trans-influence of the bridging Cl- compared to a single-bonded Cl- atom.
Version: Publisher PDF
Status: Peer reviewed
ISSN: 1600-5368
Type: Journal article
Rights: This is an Open Access article distributed under the terms of the Creative Commons Attribution License ( ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Appears in Collections:University of St Andrews Research
Chemistry Research

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