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The title compound, [Sb(C6H5)(3)(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph-3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193-198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S-N=S=N, consisting of one long S-N bond, an intermediate length N=S bond and a short S=N bond.
Slawin , A M Z , Waddell , P G & Woollins , J D 2010 , ' (Disulfur dinitrido)triphenylantimony(V) ' Acta Crystallographica. Section E, Structure reports online , vol. 66 , no. 4 , pp. M418-U768 . DOI: 10.1107/S1600536810009487
Acta Crystallographica. Section E, Structure reports online
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