(Disulfur dinitrido)triphenylantimony(V)
Abstract
The title compound, [Sb(C6H5)(3)(N2S2)], contains a molecular entity that is very similar to that of the known polymorph of Sb(S2N2)Ph-3 [Kunkel et al. (1997). Z. Naturforsch. Teil B, 52, 193-198], differing only in the orientation of the phenyl rings. The bond order in the SNSN unit is S-N=S=N, consisting of one long S-N bond, an intermediate length N=S bond and a short S=N bond.
Citation
Slawin , A M Z , Waddell , P G & Woollins , J D 2010 , ' (Disulfur dinitrido)triphenylantimony(V) ' , Acta Crystallographica. Section E, Structure reports online , vol. 66 , no. 4 , pp. M418-U768 . https://doi.org/10.1107/S1600536810009487
Publication
Acta Crystallographica. Section E, Structure reports online
Status
Peer reviewed
ISSN
1600-5368Type
Journal article
Rights
This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0 ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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