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From phenylalkylcyanamides to heterocyclic selenazadiphospholaminediselenides and carbamidoyl(phenyl) phosphinodiselenoic acids
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dc.contributor.author | Hua, Guoxiong | |
dc.contributor.author | Zhang, Qingzhi | |
dc.contributor.author | Li, Yang | |
dc.contributor.author | Slawin, Alexandra Martha Zoya | |
dc.contributor.author | Woollins, J Derek | |
dc.date.accessioned | 2011-04-04T09:04:42Z | |
dc.date.available | 2011-04-04T09:04:42Z | |
dc.date.issued | 2008-11 | |
dc.identifier | 601373 | |
dc.identifier | 9d7e9a6d-f86a-4ba5-8289-ee4b28c4b689 | |
dc.identifier | 000260023300005 | |
dc.identifier | 54049145547 | |
dc.identifier.citation | Hua , G , Zhang , Q , Li , Y , Slawin , A M Z & Woollins , J D 2008 , ' From phenylalkylcyanamides to heterocyclic selenazadiphospholaminediselenides and carbamidoyl(phenyl) phosphinodiselenoic acids ' , Dalton Transactions , no. 41 , pp. 5563-5566 . https://doi.org/10.1039/b813406p | en |
dc.identifier.issn | 1477-9226 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861563 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779275 | |
dc.identifier.uri | https://hdl.handle.net/10023/1771 | |
dc.description.abstract | The reaction of 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4- diselenide (Woollins' Reagent, WR) with phenylalkyl-cyanamides (RR'NC N, R = PhCH2CH2, R' = CH3 and R = PhCH2CH2CH2, R' = H) in refluxing toluene led to novel heterocyclic selenazadiphospholaminediselenides 1 and 2 (43% and 42% yields), the latter being hydrolyzed to the unusual zwitterionic carbamidoyl(phenyl) phosphinodiselenoic acids 3 and 4 in excellent yields (96% and 98%). | |
dc.format.extent | 4 | |
dc.format.extent | 497246 | |
dc.language.iso | eng | |
dc.relation.ispartof | Dalton Transactions | en |
dc.subject | Phosphorus-selenium Heterocycles | en |
dc.subject | Ray crystal-structures | en |
dc.subject | P-SE Heterocycles | en |
dc.subject | Woollins reagent | en |
dc.subject | Reactivity | en |
dc.subject | Derivatives | en |
dc.subject | Cynamides | en |
dc.subject | Complexes | en |
dc.subject | System | en |
dc.subject | Anions | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | From phenylalkylcyanamides to heterocyclic selenazadiphospholaminediselenides and carbamidoyl(phenyl) phosphinodiselenoic acids | en |
dc.type | Journal article | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1039/b813406p | |
dc.description.status | Peer reviewed | en |
dc.identifier.url | http://www.scopus.com/inward/record.url?scp=54049145547&partnerID=8YFLogxK | en |
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