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dc.contributor.authorHua, Guoxiong
dc.contributor.authorZhang, Qingzhi
dc.contributor.authorLi, Yang
dc.contributor.authorSlawin, Alexandra Martha Zoya
dc.contributor.authorWoollins, J Derek
dc.date.accessioned2011-04-04T09:04:42Z
dc.date.available2011-04-04T09:04:42Z
dc.date.issued2008-11
dc.identifier.citationHua , G , Zhang , Q , Li , Y , Slawin , A M Z & Woollins , J D 2008 , ' From phenylalkylcyanamides to heterocyclic selenazadiphospholaminediselenides and carbamidoyl(phenyl) phosphinodiselenoic acids ' , Dalton Transactions , no. 41 , pp. 5563-5566 . https://doi.org/10.1039/b813406pen
dc.identifier.issn1477-9226
dc.identifier.otherPURE: 601373
dc.identifier.otherPURE UUID: 9d7e9a6d-f86a-4ba5-8289-ee4b28c4b689
dc.identifier.otherWOS: 000260023300005
dc.identifier.otherScopus: 54049145547
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861563
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779275
dc.identifier.urihttp://hdl.handle.net/10023/1771
dc.description.abstractThe reaction of 2,4-bis(phenyl)-1,3-diselenadiphosphetane-2,4- diselenide (Woollins' Reagent, WR) with phenylalkyl-cyanamides (RR'NC N, R = PhCH2CH2, R' = CH3 and R = PhCH2CH2CH2, R' = H) in refluxing toluene led to novel heterocyclic selenazadiphospholaminediselenides 1 and 2 (43% and 42% yields), the latter being hydrolyzed to the unusual zwitterionic carbamidoyl(phenyl) phosphinodiselenoic acids 3 and 4 in excellent yields (96% and 98%).
dc.format.extent4
dc.language.isoeng
dc.relation.ispartofDalton Transactionsen
dc.rightsThis is the author's version of an article in Dalton Transactions. The published version (c)Royal Society of Chemistry is available from DOI: 10.1039/b813406pen
dc.subjectPhosphorus-selenium Heterocyclesen
dc.subjectRay crystal-structuresen
dc.subjectP-SE Heterocyclesen
dc.subjectWoollins reagenten
dc.subjectReactivityen
dc.subjectDerivativesen
dc.subjectCynamidesen
dc.subjectComplexesen
dc.subjectSystemen
dc.subjectAnionsen
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titleFrom phenylalkylcyanamides to heterocyclic selenazadiphospholaminediselenides and carbamidoyl(phenyl) phosphinodiselenoic acidsen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1039/b813406p
dc.description.statusPeer revieweden
dc.identifier.urlhttp://www.scopus.com/inward/record.url?scp=54049145547&partnerID=8YFLogxKen


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