A luminescent [Pd4Ru8]24+ supramolecular cage
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A phosphorescent cage of the form [Pd4Ru8]24+ is reported. The cage was formed using the metalloligand [Ru(dtbubpy)2(qpy)]2+, where qpy = 4,4’:2’,2’’:4’’,4’’’-quaterpyridine and dtbubpy = 4,4’- ditert-butyl-2,2’-bipyridine. The cage has been characterised by NMR, ESI-MS, TEM and X-ray diffraction analyses and its emission properties elucidated by steady-state and time-resolved emission spectroscopy.
Rota Martir , D , Cordes , D B , Slawin , A M Z , Escudero , D , Jacquemin , D , Warriner , S & Zysman-Colman , E 2018 , ' A luminescent [Pd 4 Ru 8 ] 24+ supramolecular cage ' , Chemical Communications , vol. 54 , no. 47 , pp. 6016-6019 . https://doi.org/10.1039/C8CC02104J
© 2018 the Authors. This work has been made available online in accordance with the publisher’s policies. This is the author created accepted version manuscript following peer review and as such may differ slightly from the final published version. The final published version of this work is available at https://doi.org/10.1039/C8CC02104J
DescriptionE.Z.-C. acknowledges the University of St Andrews and EPSRC (EP/M02105X/1) for financial support. D.E. thanks funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska- Curie grant agreement No 700961. D.J. acknowledges the RFI Lumomat for financial support.
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