Files in this item
Synthesis and structural study of (8-phenylsulfanylnaphth-1-yl)diphenylphosphine metal complexes
Item metadata
dc.contributor.author | Knight, Fergus R. | |
dc.contributor.author | Fuller, Amy L. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2011-04-01T11:01:13Z | |
dc.date.available | 2011-04-01T11:01:13Z | |
dc.date.issued | 2010-05-27 | |
dc.identifier.citation | Knight , F R , Fuller , A L , Slawin , A M Z & Woollins , J D 2010 , ' Synthesis and structural study of (8-phenylsulfanylnaphth-1-yl)diphenylphosphine metal complexes ' , Polyhedron , vol. 29 , no. 8 , pp. 1956-1963 . https://doi.org/10.1016/j.poly.2010.03.006 | en |
dc.identifier.issn | 0277-5387 | |
dc.identifier.other | PURE: 4638327 | |
dc.identifier.other | PURE UUID: 2c645573-26bd-4076-ac13-56d82bc448b6 | |
dc.identifier.other | WOS: 000278611800010 | |
dc.identifier.other | Scopus: 77953127047 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861797 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779253 | |
dc.identifier.uri | https://hdl.handle.net/10023/1764 | |
dc.description | This work is funded by the EPSCR UK | en |
dc.description.abstract | A series of three platinum(II) halide complexes 2-4 [Pt(X)(2)(Nap(PPh2)(SPh))] (Nap = naphthalene-1,8-diyl: X = Cl, Br, I) and a ruthenium(II) p-cymene complex 5 [Ru(eta(6)-(MeC6H4Pr)-Pr-i)(Cl){Nap(PPh2)(SPh)}]Cl-+(-) of the sterically crowded pen-substituted naphthalene phosphine 1 have been prepared. The compounds were fully characterised by multinuclear NMR. IR and MS and X-ray data for 1-5 are compared. Molecular structures are analysed by naphthalene ring torsions, pert-atom displacement, splay angle magnitude, P center dot center dot center dot S interactions, aromatic ring orientations and geometry around the metal centre. Platinum adopts a strictly square planar geometry which increases the distortion of the naphthalene skeleton in 2-4. Conversely, the classical-piano stool conformation of 5 results in a pseudo-octahedral conformation around the ruthenium atom which influences the naphthalene geometry to a much lesser extent with distortion of a similar magnitude to the free ligand 1. (c) 2010 Elsevier Ltd. All rights reserved. | |
dc.format.extent | 8 | |
dc.language.iso | eng | |
dc.relation.ispartof | Polyhedron | en |
dc.rights | This is the author's version of an article in Polyhedron. The published version (c)Elsevier is available from http://www.sciencedirect.com | en |
dc.subject | Naphthalene | en |
dc.subject | Peri-Substitution | en |
dc.subject | Platinum | en |
dc.subject | Ruthenium | en |
dc.subject | Complex | en |
dc.subject | Phosphine | en |
dc.subject | Sulfur | en |
dc.subject | X-ray structure | en |
dc.subject | PI-PI Stacking | en |
dc.subject | Polyaromatic hydrocarbon ligands | en |
dc.subject | Platinum complexes | en |
dc.subject | Coordination chemistry | en |
dc.subject | Hemilabile ligands | en |
dc.subject | Crystal-structures | en |
dc.subject | Phosphinothiolato complexes | en |
dc.subject | Catalytic carbonylation | en |
dc.subject | Palladium complexes | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Synthesis and structural study of (8-phenylsulfanylnaphth-1-yl)diphenylphosphine metal complexes | en |
dc.type | Journal article | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1016/j.poly.2010.03.006 | |
dc.description.status | Peer reviewed | en |
This item appears in the following Collection(s)
Items in the St Andrews Research Repository are protected by copyright, with all rights reserved, unless otherwise indicated.