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dc.contributor.authorKnight, Fergus R.
dc.contributor.authorFuller, Amy L.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2011-04-01T11:01:08Z
dc.date.available2011-04-01T11:01:08Z
dc.date.issued2010-05-10
dc.identifier4638293
dc.identifiere30a1944-f5b6-4833-a763-a0d8f5be2c01
dc.identifier000278238300019
dc.identifier77951206116
dc.identifier.citationKnight , F R , Fuller , A L , Slawin , A M Z & Woollins , J D 2010 , ' Preparation and compounds of (8-methoxynaphth-1-yl)diphenylphosphine ' , Polyhedron , vol. 29 , no. 7 , pp. 1849-1853 . https://doi.org/10.1016/j.poly.2010.02.033en
dc.identifier.issn0277-5387
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861512
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779254
dc.identifier.urihttps://hdl.handle.net/10023/1763
dc.description.abstractReaction of 8-methoxy-1-naphthyllithium (2) with one equivalent of chlorodiphenylphosphine gives the novel (8-methoxynaphth-1-yl)diphenylphosphine (3) which was oxidised to the corresponding sulfide (4) and selenide (5) by reaction with sulfur and selenium, respectively. The P center dot center dot center dot O peri distance is significantly increased in 4 and 5 at 2.819(3)[2.793(3)] and 2.827(3) [2.806(3)] angstrom [values in square brackets are for the second independent molecules in each case] relative to the value in 3 of 2.678(2) angstrom. There are short E center dot center dot center dot O interactions ie O(1)center dot center dot center dot S(1) 3.165(3) [3.124(3)], 0(1)center dot center dot center dot Se(1) 3.247(3) [3.200(2)] angstrom and these may be repulsive and responsible for the increased P center dot center dot center dot O separation. The use of the naphthalene backbone in the synthesis of a potential hemilabile ligand is demonstrated by the synthesis and X-ray structure of (8-methoxynaphth-1-yl)diethoxyphosphine ruthenium p-cymene dichloride (6). (C) 2010 Elsevier Ltd. All rights reserved.
dc.format.extent5
dc.format.extent450067
dc.language.isoeng
dc.relation.ispartofPolyhedronen
dc.subjectLiganden
dc.subjectPhosphorusen
dc.subjectX-ray structureen
dc.subjectPeri substitutionen
dc.subjectCoordination chemistryen
dc.subjectAsymmetric catalysisen
dc.subjectHemilabile ligandsen
dc.subjectMetal-complexesen
dc.subjectSystemsen
dc.subjectBonden
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titlePreparation and compounds of (8-methoxynaphth-1-yl)diphenylphosphineen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.identifier.doi10.1016/j.poly.2010.02.033
dc.description.statusPeer revieweden


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