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Preparation and compounds of (8-methoxynaphth-1-yl)diphenylphosphine
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dc.contributor.author | Knight, Fergus R. | |
dc.contributor.author | Fuller, Amy L. | |
dc.contributor.author | Slawin, Alexandra M. Z. | |
dc.contributor.author | Woollins, J. Derek | |
dc.date.accessioned | 2011-04-01T11:01:08Z | |
dc.date.available | 2011-04-01T11:01:08Z | |
dc.date.issued | 2010-05-10 | |
dc.identifier.citation | Knight , F R , Fuller , A L , Slawin , A M Z & Woollins , J D 2010 , ' Preparation and compounds of (8-methoxynaphth-1-yl)diphenylphosphine ' , Polyhedron , vol. 29 , no. 7 , pp. 1849-1853 . https://doi.org/10.1016/j.poly.2010.02.033 | en |
dc.identifier.issn | 0277-5387 | |
dc.identifier.other | PURE: 4638293 | |
dc.identifier.other | PURE UUID: e30a1944-f5b6-4833-a763-a0d8f5be2c01 | |
dc.identifier.other | WOS: 000278238300019 | |
dc.identifier.other | Scopus: 77951206116 | |
dc.identifier.other | ORCID: /0000-0002-9527-6418/work/56861512 | |
dc.identifier.other | ORCID: /0000-0002-1498-9652/work/31779254 | |
dc.identifier.uri | https://hdl.handle.net/10023/1763 | |
dc.description.abstract | Reaction of 8-methoxy-1-naphthyllithium (2) with one equivalent of chlorodiphenylphosphine gives the novel (8-methoxynaphth-1-yl)diphenylphosphine (3) which was oxidised to the corresponding sulfide (4) and selenide (5) by reaction with sulfur and selenium, respectively. The P center dot center dot center dot O peri distance is significantly increased in 4 and 5 at 2.819(3)[2.793(3)] and 2.827(3) [2.806(3)] angstrom [values in square brackets are for the second independent molecules in each case] relative to the value in 3 of 2.678(2) angstrom. There are short E center dot center dot center dot O interactions ie O(1)center dot center dot center dot S(1) 3.165(3) [3.124(3)], 0(1)center dot center dot center dot Se(1) 3.247(3) [3.200(2)] angstrom and these may be repulsive and responsible for the increased P center dot center dot center dot O separation. The use of the naphthalene backbone in the synthesis of a potential hemilabile ligand is demonstrated by the synthesis and X-ray structure of (8-methoxynaphth-1-yl)diethoxyphosphine ruthenium p-cymene dichloride (6). (C) 2010 Elsevier Ltd. All rights reserved. | |
dc.format.extent | 5 | |
dc.language.iso | eng | |
dc.relation.ispartof | Polyhedron | en |
dc.rights | This is the author's version of an article published in Polyhedron. The published version (c) Elsevier is available from http://www.sciencedirect.com | en |
dc.subject | Ligand | en |
dc.subject | Phosphorus | en |
dc.subject | X-ray structure | en |
dc.subject | Peri substitution | en |
dc.subject | Coordination chemistry | en |
dc.subject | Asymmetric catalysis | en |
dc.subject | Hemilabile ligands | en |
dc.subject | Metal-complexes | en |
dc.subject | Systems | en |
dc.subject | Bond | en |
dc.subject | QD Chemistry | en |
dc.subject.lcc | QD | en |
dc.title | Preparation and compounds of (8-methoxynaphth-1-yl)diphenylphosphine | en |
dc.type | Journal article | en |
dc.description.version | Postprint | en |
dc.contributor.institution | University of St Andrews. School of Chemistry | en |
dc.contributor.institution | University of St Andrews. EaSTCHEM | en |
dc.identifier.doi | https://doi.org/10.1016/j.poly.2010.02.033 | |
dc.description.status | Peer reviewed | en |
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