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dc.contributor.authorKnight, Fergus R.
dc.contributor.authorFuller, Amy L.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2011-04-01T11:01:08Z
dc.date.available2011-04-01T11:01:08Z
dc.date.issued2010-05-10
dc.identifier.citationKnight , F R , Fuller , A L , Slawin , A M Z & Woollins , J D 2010 , ' Preparation and compounds of (8-methoxynaphth-1-yl)diphenylphosphine ' , Polyhedron , vol. 29 , no. 7 , pp. 1849-1853 . https://doi.org/10.1016/j.poly.2010.02.033en
dc.identifier.issn0277-5387
dc.identifier.otherPURE: 4638293
dc.identifier.otherPURE UUID: e30a1944-f5b6-4833-a763-a0d8f5be2c01
dc.identifier.otherWOS: 000278238300019
dc.identifier.otherScopus: 77951206116
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861512
dc.identifier.otherORCID: /0000-0002-1498-9652/work/31779254
dc.identifier.urihttp://hdl.handle.net/10023/1763
dc.description.abstractReaction of 8-methoxy-1-naphthyllithium (2) with one equivalent of chlorodiphenylphosphine gives the novel (8-methoxynaphth-1-yl)diphenylphosphine (3) which was oxidised to the corresponding sulfide (4) and selenide (5) by reaction with sulfur and selenium, respectively. The P center dot center dot center dot O peri distance is significantly increased in 4 and 5 at 2.819(3)[2.793(3)] and 2.827(3) [2.806(3)] angstrom [values in square brackets are for the second independent molecules in each case] relative to the value in 3 of 2.678(2) angstrom. There are short E center dot center dot center dot O interactions ie O(1)center dot center dot center dot S(1) 3.165(3) [3.124(3)], 0(1)center dot center dot center dot Se(1) 3.247(3) [3.200(2)] angstrom and these may be repulsive and responsible for the increased P center dot center dot center dot O separation. The use of the naphthalene backbone in the synthesis of a potential hemilabile ligand is demonstrated by the synthesis and X-ray structure of (8-methoxynaphth-1-yl)diethoxyphosphine ruthenium p-cymene dichloride (6). (C) 2010 Elsevier Ltd. All rights reserved.
dc.format.extent5
dc.language.isoeng
dc.relation.ispartofPolyhedronen
dc.rightsThis is the author's version of an article published in Polyhedron. The published version (c) Elsevier is available from http://www.sciencedirect.comen
dc.subjectLiganden
dc.subjectPhosphorusen
dc.subjectX-ray structureen
dc.subjectPeri substitutionen
dc.subjectCoordination chemistryen
dc.subjectAsymmetric catalysisen
dc.subjectHemilabile ligandsen
dc.subjectMetal-complexesen
dc.subjectSystemsen
dc.subjectBonden
dc.subjectQD Chemistryen
dc.subject.lccQDen
dc.titlePreparation and compounds of (8-methoxynaphth-1-yl)diphenylphosphineen
dc.typeJournal articleen
dc.description.versionPostprinten
dc.contributor.institutionUniversity of St Andrews.School of Chemistryen
dc.contributor.institutionUniversity of St Andrews.EaSTCHEMen
dc.identifier.doihttps://doi.org/10.1016/j.poly.2010.02.033
dc.description.statusPeer revieweden


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