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dc.contributor.authorHua, Guoxiong
dc.contributor.authorCordes, David B.
dc.contributor.authorSlawin, Alexandra M. Z.
dc.contributor.authorWoollins, J. Derek
dc.date.accessioned2019-04-18T23:38:06Z
dc.date.available2019-04-18T23:38:06Z
dc.date.issued2018-04-19
dc.identifier252589097
dc.identifier2470cfdd-1e47-4475-ab6c-42ab63d0c9a2
dc.identifier85046021908
dc.identifier000435602300016
dc.identifier.citationHua , G , Cordes , D B , Slawin , A M Z & Woollins , J D 2018 , ' Application of one-pot three-component condensation reaction for the synthesis of new organophosphorus-sulfur macrocycles ' , Synlett , vol. eFirst . https://doi.org/10.1055/s-0037-1609666en
dc.identifier.issn0936-5214
dc.identifier.otherORCID: /0000-0002-5366-9168/work/44629791
dc.identifier.otherORCID: /0000-0002-9527-6418/work/56861718
dc.identifier.otherORCID: /0000-0002-1498-9652/work/59464681
dc.identifier.urihttps://hdl.handle.net/10023/17544
dc.description.abstractAn efficient approach has been developed for the synthesis of new phosphorus–sulfur heterocycles by a one-pot three-component condensation reaction of a four-membered-ring thionation reagent [Lawesson’s reagent or its ferrocene analogue (2,4-diferrocenyl-1,3,2,4-diathiadiphosphetane 2,4-disulfide)], an alkane- or arenedithiol, and a dihaloalkane at room temperature in the presence of triethylamine. The simple synthesis method with mild conditions (room temperature and normal reactant concentrations) enhances further the application of the multicomponent reaction in the preparation of novel phosphorus–sulfur heterocycles. Six representative X-ray structures confirmed the formation of these macrocycles.
dc.format.extent1489101
dc.format.extent2413914
dc.language.isoeng
dc.relation.ispartofSynletten
dc.subjectMulticomponent reactionsen
dc.subjectMacrocyclesen
dc.subjectPhosphorus-sulfur heterocyclesen
dc.subjectLawesson's reagenten
dc.subjectDithiolsen
dc.subjectDihaloalkanesen
dc.subjectQD Chemistryen
dc.subjectDASen
dc.subject.lccQDen
dc.titleApplication of one-pot three-component condensation reaction for the synthesis of new organophosphorus-sulfur macrocyclesen
dc.typeJournal articleen
dc.contributor.institutionUniversity of St Andrews. School of Chemistryen
dc.contributor.institutionUniversity of St Andrews. EaSTCHEMen
dc.contributor.institutionUniversity of St Andrews. Office of the Principalen
dc.identifier.doi10.1055/s-0037-1609666
dc.description.statusPeer revieweden
dc.date.embargoedUntil2019-04-19


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